| Synthesis and characterization of high voltage electrodeposited phosphorus doped DLC films | |
| Department | 固体润滑国家重点实验室 |
Wan SH(万善宏) ; Hu HY(胡红艳); Chen G(陈刚); Zhang JY(张俊彦)
| |
| 2008 | |
| Source Publication | Electrochemistry Communications
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| ISSN | 1388-2481 |
| Volume | 10Pages:461-465 |
| Abstract | Phosphorus doped diamond like carbon (DLC) films were firstly synthesized by the electrolysis of methanol-Triphenylphosphorus (PPh3) solution under high voltage, atmospheric pressure and low temperature. The microstructure and morphology of the as-deposited films were analyzed by Raman spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy. The measurements results suggested that phosphorus doping enhanced the carbon films graphitization and the doped phosphorus existed mainly in C@P bonds with the P/C ratio of 0.034. The P-DLC films have larger surface roughness compared to the DLC film. Moreover, the formation of P-DLC films in liquid-phase electrodeposition was via the reactions of the –CH3 and –P groups to form CPx network. |
| Keyword | Dlc Phosphorus Carbide Electrodeposition Growth Mechanism |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | National Natural Science Foundation of China (NSFC) with Grant No. 50572108, No. 50772115;the ‘‘Hundreds Talent Program” of Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 纳米润滑研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2601 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Zhang JY(张俊彦) |
| Recommended Citation GB/T 7714 | Wan SH,Hu HY,Chen G,et al. Synthesis and characterization of high voltage electrodeposited phosphorus doped DLC films[J]. Electrochemistry Communications,2008,10:461-465. |
| APA | 万善宏,胡红艳,陈刚,&张俊彦.(2008).Synthesis and characterization of high voltage electrodeposited phosphorus doped DLC films.Electrochemistry Communications,10,461-465. |
| MLA | 万善宏,et al."Synthesis and characterization of high voltage electrodeposited phosphorus doped DLC films".Electrochemistry Communications 10(2008):461-465. |
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| File Name/Size | DocType | Version | Access | License | ||
| 2008461-465.PDF（461KB） | 开放获取 | License | View Application Full Text | |||
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