| Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst | |
| Department | OSSO国家重点实验室 |
Hangkong, Yuan1 ; Bright T. Kusema2; Zhen, Yan2; Stéphane Streiff2; Feng, Shi1
| |
| The second department | 纳米催化课题组 |
| 2019-11 | |
| Source Publication | RSC Advances
 |
| Volume | 9Issue:66Pages:38877 - 38881 |
| Abstract | The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlOxcatalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu4Ni1Al4Ox was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource. |
| Keyword | 2,5-bis(aminomethyl)furan 5-(hydroxymethyl)furfural bifunctional catalyst CuNiAlOx amination |
| MOST Discipline Catalogue | 理学::化学 |
| DOI | 10.1039/C9RA08560B |
| URL | 查看原文 |
| If | 3.049 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/25965 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Bright T. Kusema; Feng, Shi |
| Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 2.Eco-Efficient Products and Processes Laboratory (E2P2L), UMI 3464 CNRS-Solvay |
| Recommended Citation GB/T 7714 | Hangkong, Yuan,Bright T. Kusema,Zhen, Yan,et al. Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst[J]. RSC Advances,2019,9(66):38877 - 38881. |
| APA | Hangkong, Yuan,Bright T. Kusema,Zhen, Yan,Stéphane Streiff,&Feng, Shi.(2019).Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst.RSC Advances,9(66),38877 - 38881. |
| MLA | Hangkong, Yuan,et al."Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst".RSC Advances 9.66(2019):38877 - 38881. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| RSC Advance.pdf（756KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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