Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon | |
Department | 固体润滑国家重点实验室 |
Mo YF(莫宇飞); 于波(男); Zhao WJ(赵文杰); Bai MW(白明武) | |
2008 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 255Issue:无期Pages:2276-2283 |
Abstract | A series of 1-alkyl-3-ethylcarboxylic acid imidazolium chloride ([AEImi][Cl]) ionic liquids was synthesized and evaluated as a new kind of lubricant for microelectromechanical system (MEMS). In this research, novel molecular thin ionic liquid films (ILs) with various bonding percentages were prepared with different annealing temperatures and times. Film wettability was determined by measurement of contact angle and thickness with the ellipsometric method. The chemical composition, structure and morphology were characterized by the means of multi-technique X-ray photoelectron spectrometric, and atomic force microscopic analysis, respectively. The nano- and microtribological properties of the ionic liquid film were investigated. The morphologies of wear tracks of IL films were examined using a 3D non-contact profilometer. The influence of chain length on friction in nano-scale, and the effect of bonding percentage and sliding frequency on friction coefficient, carry-bearing capacity and durability in micro-scale were studied. Data are compared to the perfluoropolyether lubricant Z Dol. The [AEImi][Cl] ionic liquid films with appropriate bonding percentage exhibited comparable loadbearing capacity and durability than Z Dol 3800 at thickness level of several nanometers. Therefore, the[AEImi][Cl] ionic liquid filmshows strong potential applications involving the lubrication and protectionof MEMS. |
Keyword | Ionic Liquid Bonding Percentage Tribology Mems |
Subject Area | 材料科学与物理化学 |
Funding Organization | Innovative Group Foundation from National Natural Science Foundation of China (NSFC) under Grant Number 50421502;National 973 Program 2007CB607601;NSFC 50675217;‘‘100 Talents’’ Program of Chinese Academy of Sciences |
Indexed By | SCI |
Language | 英语 |
Funding Project | 材料表面与界面行为研究组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2578 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Bai MW(白明武) |
Recommended Citation GB/T 7714 | Mo YF,Yu B,Zhao WJ,et al. Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon[J]. Applied Surface Science,2008,255(无期):2276-2283. |
APA | 莫宇飞,于波,赵文杰,&白明武.(2008).Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon.Applied Surface Science,255(无期),2276-2283. |
MLA | 莫宇飞,et al."Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon".Applied Surface Science 255.无期(2008):2276-2283. |
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