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Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon
Department固体润滑国家重点实验室
Mo YF(莫宇飞); 于波(男); Zhao WJ(赵文杰); Bai MW(白明武)
2008
Source PublicationApplied Surface Science
ISSN0169-4332
Volume255Issue:无期Pages:2276-2283
AbstractA series of 1-alkyl-3-ethylcarboxylic acid imidazolium chloride ([AEImi][Cl]) ionic liquids was synthesized and evaluated as a new kind of lubricant for microelectromechanical system (MEMS). In this research, novel molecular thin ionic liquid films (ILs) with various bonding percentages were prepared with different annealing temperatures and times. Film wettability was determined by measurement of contact angle and thickness with the ellipsometric method. The chemical composition, structure and morphology were characterized by the means of multi-technique X-ray photoelectron spectrometric, and atomic force microscopic analysis, respectively. The nano- and microtribological properties of the ionic liquid film were investigated. The morphologies of wear tracks of IL films were examined using a 3D non-contact profilometer. The influence of chain length on friction in nano-scale, and the effect of bonding percentage and sliding frequency on friction coefficient, carry-bearing capacity and durability in micro-scale were studied. Data are compared to the perfluoropolyether lubricant Z Dol. The [AEImi][Cl] ionic liquid films with appropriate bonding percentage exhibited comparable loadbearing capacity and durability than Z Dol 3800 at thickness level of several nanometers. Therefore, the[AEImi][Cl] ionic liquid filmshows strong potential applications involving the lubrication and protectionof MEMS.
KeywordIonic Liquid Bonding Percentage Tribology Mems
Subject Area材料科学与物理化学
Funding OrganizationInnovative Group Foundation from National Natural Science Foundation of China (NSFC) under Grant Number 50421502;National 973 Program 2007CB607601;NSFC 50675217;‘‘100 Talents’’ Program of Chinese Academy of Sciences
Indexed BySCI
Language英语
Funding Project材料表面与界面行为研究组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/2578
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorBai MW(白明武)
Recommended Citation
GB/T 7714
Mo YF,Yu B,Zhao WJ,et al. Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon[J]. Applied Surface Science,2008,255(无期):2276-2283.
APA 莫宇飞,于波,赵文杰,&白明武.(2008).Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon.Applied Surface Science,255(无期),2276-2283.
MLA 莫宇飞,et al."Microtribological properties of molecularly thin carboxylic acid functionalized imidazolium ionic liquid film on single-crystal silicon".Applied Surface Science 255.无期(2008):2276-2283.
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