Solid-phase extraction of phenoxyacetic acid herbicides in complex samples with Zr(IV)-based metal-organic framework | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Tiantian Si1,2; Lei Liu3; Xiaojing Liang1; Huixiao Duo1,2; Licheng Wang1; ShuaiWang1 | |
The second department | 色谱填料与分析技术组 |
2019-04 | |
Source Publication | Journal of Separation Science |
Volume | 42Issue:12Pages:2148-2154 |
Abstract | A zirconium (IV)-based metal organic framework material (MOF-808) has been synthesized in a simple way and used for extraction of phenoxyacetic acids in complex samples. The material has good thermal and chemical stability, large specific surface area (905.36 m²/g) and high pore size (22.18 Å). Besides, it contains a large amount of Zr-O groups, easy to form Zr-O-H bond with carboxyl groups of phenoxyacetic acids, and possesses biphenyl skeleton structure, easy to interact with compounds through π-π and hydrophobic interactions. The characteristics make the material very suitable for extraction of certain compounds with high extraction efficiency and excellent selectivity. The extraction conditions were optimized, and then an analytical method was successfully established and applied for analysis of actual samples. The solid phase extraction method based on prepared material had a wide linear range of 0.2-250 ug·L-1 and a low detection limit of 0.1-0.5 ug·L-1 for four phenoxyacetic acid compounds including 2,4-dichlorophenoxyacetic acid, 2-(2,4-dichlorophenoxy) propionic acid, 4-chlorophenoxyacetic acid and dicamba. The relative standard deviations of intraday and interday were between 1.8-3.8% and 4.3-6.9%, and the recoveries of spiking were between 77.1%-109.3%. The results showed the material is a desired substituent for the extraction of compounds with benzene ring structure containing carboxyl groups. |
Keyword | High-performance liquid chromatography Metal-organic frameworks Phenoxyacetic acid herbicides Solid-phase extraction |
MOST Discipline Catalogue | 理学 |
DOI | 10.1002/jssc.201900243 |
If | 2.516 |
Language | 英语 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/25736 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Licheng Wang; ShuaiWang |
Affiliation | 1.1CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.2University of Chinese Academy of Sciences, Beijing 100049, China 3.Exploration and Development Research Institute, Changqing Oilfield, Xi'an, China |
Recommended Citation GB/T 7714 | Tiantian Si,Lei Liu,Xiaojing Liang,et al. Solid-phase extraction of phenoxyacetic acid herbicides in complex samples with Zr(IV)-based metal-organic framework[J]. Journal of Separation Science,2019,42(12):2148-2154. |
APA | Tiantian Si,Lei Liu,Xiaojing Liang,Huixiao Duo,Licheng Wang,&ShuaiWang.(2019).Solid-phase extraction of phenoxyacetic acid herbicides in complex samples with Zr(IV)-based metal-organic framework.Journal of Separation Science,42(12),2148-2154. |
MLA | Tiantian Si,et al."Solid-phase extraction of phenoxyacetic acid herbicides in complex samples with Zr(IV)-based metal-organic framework".Journal of Separation Science 42.12(2019):2148-2154. |
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808萃取苯氧乙酸paper.pdf(668KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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