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Synthesis of hydrothermally reduced graphene/MnO2 composites and their electrochemical properties as supercapacitors
Department固体润滑国家重点实验室
Li ZP(李章朋); Wang JQ(王金清); Liu S(刘胜); Liu XH(刘晓红); Yang SR(杨生荣)
2011
Source PublicationJournal of Power Sources
ISSN0378-7753
Volume196Pages:8160-8165
AbstractHydrothermally reduced graphene/MnO2 (HRG/MnO2) composites were synthesized by dipping HRG into the mixed aqueous solution of 0.1 M KMnO4 and 0.1 M K2SO4 for different periods of time at room temperature. The morphology and microstructure of the as-prepared composites were characterized by field-emission scanning electron microscopy, X-ray diffraction, Raman microscope, and X-ray photoelec- tron spectroscopy. The characterizations indicate that MnO2 successfully deposited on HRG surfaces and the morphology of the HRG/MnO2 shows a three-dimensional porous structure with MnO2 homoge- nously distributing on the HRG surfaces. Capacitive properties of the synthesized composite electrodes were studied using cyclic voltammetry and electrochemical impedance spectroscopy in a three-electrode experimental setup using 1 M Na2SO4 aqueous solution as electrolyte. The main results of electrochem- ical tests are drawn as followsthe specific capacitance value of HRG/MnO2–200 (HRG dipped into the mixed solution of 0.1 M KMnO4 and 0.1 M K2SO4 for 200 min) electrode reached 211.5 F g−1 at a potential scan rate of 2 mV s−1; moreover, this electrode shows a good cyclic stability and capacity retention. It is anticipated that the synthesized HRG/MnO2 composites will find promising applications in superca- pacitors and other devices in virtue of their outstanding characters of good cycle stability, low cost and environmentally benign nature.
KeywordGraphene Mno2 Composite Supercapacitor
Subject Area材料科学与物理化学
Funding Organizationthe National Natural Science Foundation of China (Grant Nos. 20823008;51075384);“Top Hundred Talents Program” of Chinese Academy of Sciences
Indexed BySCI
Language英语
Funding Project聚合物摩擦学组
Citation statistics
Cited Times:211[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/2466
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang JQ(王金清); Yang SR(杨生荣)
Recommended Citation
GB/T 7714
Li ZP,Wang JQ,Liu S,et al. Synthesis of hydrothermally reduced graphene/MnO2 composites and their electrochemical properties as supercapacitors[J]. Journal of Power Sources,2011,196:8160-8165.
APA 李章朋,王金清,刘胜,刘晓红,&杨生荣.(2011).Synthesis of hydrothermally reduced graphene/MnO2 composites and their electrochemical properties as supercapacitors.Journal of Power Sources,196,8160-8165.
MLA 李章朋,et al."Synthesis of hydrothermally reduced graphene/MnO2 composites and their electrochemical properties as supercapacitors".Journal of Power Sources 196(2011):8160-8165.
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