| Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides | |
| Department | 绿色化学研究发展中心 |
Cui XJ(崔新江) ; Zhang Y(张妍); Shi F(石峰); Deng YQ(邓友全)
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| 2011 | |
| Source Publication | Chem. Eur. J.
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| ISSN | 0947-6539 |
| Volume | 17Pages:1021-1028 |
| Abstract | Complicated and expensive organic ligands are normally essential in fine chemical synthesis at preparative or industrial levels. The synthesis of fine chemicals by using heterogeneous catalyst systems without additive organic ligand is highly desirable but severely limited due to their poor generality and rigorous reaction conditions. Here, we show the results of carbon–nitrogen or carbon–carbonbond formation catalyzed by an Ag/Mo hybrid material with specific Ag6Mo10O33 crystal structure. 48 nitrogen-or oxygen-containing compounds, that is, amines, carboxamides, sulfonamides, and ketones, were successfully synthesized through a borrowing-hydrogen mechanism. Up to 99% isolated yields were obtained under relatively mild conditions without additive organic ligand. The catalytic process shows promise for the efficient and economic synthesis of amine, carboxamide, sulfonamide, and ketone derivatives because of the simplicity of the system and ease of operation. |
| Keyword | Ag/mo Amines Carboxamides Ketones Sulfonamides |
| Subject Area | 物理化学 |
| Funding Organization | the “Hundred Talents Program” of the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2378 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Shi F(石峰) |
| Recommended Citation GB/T 7714 | Cui XJ,Zhang Y,Shi F,et al. Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides[J]. Chem. Eur. J.,2011,17:1021-1028. |
| APA | 崔新江,张妍,石峰,&邓友全.(2011).Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides.Chem. Eur. J.,17,1021-1028. |
| MLA | 崔新江,et al."Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides".Chem. Eur. J. 17(2011):1021-1028. |
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