Cobalt modified N-doped carbon nanotubes for catalytic C=C bond formation via dehydrogenative coupling of benzyl alcohols and DMSO | |
Department | 苏州研究院 |
Li JL(李金磊)1,2; Liu GL(刘国亮)1; Shi LJ(石利军)1,2; Xing Q(邢琦)1; Li FW(李福伟)1; Li FW(李福伟) | |
The second department | osso国家重点实验室 |
2017 | |
Source Publication | Green Chemistry |
ISSN | 1463-9262 |
Volume | 19Issue:24Pages:5782-5788 |
Abstract | The development of heterogeneous, cost-effective and environmentally benign catalysts to construct CC bonds is highly desirable. We report here Co@N-doped carbon nanotubes (Co@NCNT) as a catalyst for a novel synthesis of styryl sulfides via dehydrogenative coupling of benzyl alcohols and DMSO under anaerobic conditions. This reaction maintains high atom efficiency as the CC bond is formed without the cracking of the C–S bond. We proposed that Co modified N-doped carbon sites are the active sites, different from traditionally believed metal centers for dehydrogenative C–C coupling. Moreover, the Co@NCNT catalyst could be easily separated and recycled for at least six runs. This work opens up a new application of metal–N–C catalysts in CC bond-forming reactions in synthetic chemistry. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c7gc02335a |
Funding Organization | Key Research Program of Frontier Sciences of Chinese Academy of Science (QYZDJ-SSWSLH051);the National Natural Science Foundation of China (21503242;21522309; 21603244;21773271);Suzhou Science and Technology Projects (SYG201518;SYG201519) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 均相催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23784 |
Collection | 苏州研究院 |
Corresponding Author | Li FW(李福伟) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Li JL,Liu GL,Shi LJ,et al. Cobalt modified N-doped carbon nanotubes for catalytic C=C bond formation via dehydrogenative coupling of benzyl alcohols and DMSO[J]. Green Chemistry,2017,19(24):5782-5788. |
APA | Li JL,Liu GL,Shi LJ,Xing Q,Li FW,&李福伟.(2017).Cobalt modified N-doped carbon nanotubes for catalytic C=C bond formation via dehydrogenative coupling of benzyl alcohols and DMSO.Green Chemistry,19(24),5782-5788. |
MLA | Li JL,et al."Cobalt modified N-doped carbon nanotubes for catalytic C=C bond formation via dehydrogenative coupling of benzyl alcohols and DMSO".Green Chemistry 19.24(2017):5782-5788. |
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c7gc02335a.pdf(1192KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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