Sustainable Catalytic Amination of Diols: From Cycloamination to Monoamination | |
Department | OSSO国家重点实验室 |
Wu YJ(吴亚娟)1,2; Yuan HK(袁航空)1; Shi F(石峰)1; Shi F(石峰) | |
2018 | |
Source Publication | ACS Sustainable Chemistry and Engineering |
ISSN | 2168-0485 |
Volume | 6Issue:1Pages:1061-1067 |
Abstract | N-Alkyl amines are extensively applied in the synthesis of functional materials, pharmaceuticals, and pesticides. The reaction of diols with amines is attractive and has been investigated for more than 30 years by using iridium, ruthenium, and other catalysts. However, the main products with diols as starting materials, especially for C4–C6 diols, are N-heterocyclic compounds because cyclization reaction is favorable in thermodynamics. Here, for the first time, a simple and non-noble catalyst CuNiAlOx prepared by a coprecipitation method was developed for the reaction of C4–C6 diols with amines to give monoamination products. This method offers an efficient and environmentally friendly method for the selective monoamination of diols. |
Keyword | Diols Amines Monoamination Non-noble Metal Catalyst |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acssuschemeng.7b03373 |
Funding Organization | the National Key Research and Development Program of China (2017YFA0403100) ; National Natural Science Foundation of China (21633013) ; Key Research Program of Frontier Sciences of CAS (QYZDJ-SSW-SLH051) |
Indexed By | SCI |
If | 6.14 |
Language | 英语 |
Funding Project | 纳米催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23777 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Shi F(石峰) |
Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, 18 Tianshui Middle Rd, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Wu YJ,Yuan HK,Shi F,et al. Sustainable Catalytic Amination of Diols: From Cycloamination to Monoamination[J]. ACS Sustainable Chemistry and Engineering,2018,6(1):1061-1067. |
APA | Wu YJ,Yuan HK,Shi F,&Shi F.(2018).Sustainable Catalytic Amination of Diols: From Cycloamination to Monoamination.ACS Sustainable Chemistry and Engineering,6(1),1061-1067. |
MLA | Wu YJ,et al."Sustainable Catalytic Amination of Diols: From Cycloamination to Monoamination".ACS Sustainable Chemistry and Engineering 6.1(2018):1061-1067. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
acssuschemeng.7b0337(4242KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment