LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst
DepartmentOSSO国家重点实验室
Wang PX(王培学)1,2,3; Fei YQ(费玉清)1,2; Deng YQ(邓友全)1,2,3; Deng YQ(邓友全)
The second department固体润滑国家重点实验室;青岛研发中心/青岛市资源化学与新材料研究中心
2018
Source PublicationNew Journal of Chemistry
ISSN1144-0546
Volume42Issue:2Pages:1202-1207
Abstract

A series of amino triazole alkali salts (MATriz, M was Li, Na, K) were prepared, characterized and used for the direct synthesis of polyureas from CO2 and diamines. Under the reaction conditions of an initial pressure of CO2 of 4 MPa, 170 °C, 8 h, good to excellent yields of various polyureas were achieved over the KATriz catalyst. According to the results of the characterization of the MATriz catalyst, it was found that the catalytic performance is essentially consistent with the basicity of salts. Besides, the catalyst could be easily recycled and reused for several runs without obvious deactivation.

Subject Area物理化学与绿色催化
DOI10.1039/c7nj04197g
Funding Organizationthe National Natural Science Foundation of China (No. 21173240) ; CAS ‘‘Light of West China’’ Program
Indexed BySCI
If3.201
Language英语
Funding Project绿色催化研究组
compositor第一作者单位
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/23763
Collection羰基合成与选择氧化国家重点实验室(OSSO)
固体润滑国家重点实验室(LSL)
青岛研发中心/青岛市资源化学与新材料研究中心
Corresponding AuthorDeng YQ(邓友全)
Affiliation1.Chinese Acad Sci, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, State Key Lab Solid Luburicat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China
3.Qingdao Ctr Resource Chem & New Mat, Qingdao 266100, Peoples R China
Recommended Citation
GB/T 7714
Wang PX,Fei YQ,Deng YQ,et al. Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst[J]. New Journal of Chemistry,2018,42(2):1202-1207.
APA Wang PX,Fei YQ,Deng YQ,&Deng YQ.(2018).Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst.New Journal of Chemistry,42(2),1202-1207.
MLA Wang PX,et al."Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst".New Journal of Chemistry 42.2(2018):1202-1207.
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