Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst | |
Department | OSSO国家重点实验室 |
Wang PX(王培学)1,2,3; Fei YQ(费玉清)1,2; Deng YQ(邓友全)1,2,3; Deng YQ(邓友全) | |
The second department | 固体润滑国家重点实验室;青岛研发中心/青岛市资源化学与新材料研究中心 |
2018 | |
Source Publication | New Journal of Chemistry |
ISSN | 1144-0546 |
Volume | 42Issue:2Pages:1202-1207 |
Abstract | A series of amino triazole alkali salts (MATriz, M was Li, Na, K) were prepared, characterized and used for the direct synthesis of polyureas from CO2 and diamines. Under the reaction conditions of an initial pressure of CO2 of 4 MPa, 170 °C, 8 h, good to excellent yields of various polyureas were achieved over the KATriz catalyst. According to the results of the characterization of the MATriz catalyst, it was found that the catalytic performance is essentially consistent with the basicity of salts. Besides, the catalyst could be easily recycled and reused for several runs without obvious deactivation. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c7nj04197g |
Funding Organization | the National Natural Science Foundation of China (No. 21173240) ; CAS ‘‘Light of West China’’ Program |
Indexed By | SCI |
If | 3.201 |
Language | 英语 |
Funding Project | 绿色催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23763 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 固体润滑国家重点实验室(LSL) 青岛研发中心/青岛市资源化学与新材料研究中心 |
Corresponding Author | Deng YQ(邓友全) |
Affiliation | 1.Chinese Acad Sci, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, State Key Lab Solid Luburicat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 3.Qingdao Ctr Resource Chem & New Mat, Qingdao 266100, Peoples R China |
Recommended Citation GB/T 7714 | Wang PX,Fei YQ,Deng YQ,et al. Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst[J]. New Journal of Chemistry,2018,42(2):1202-1207. |
APA | Wang PX,Fei YQ,Deng YQ,&Deng YQ.(2018).Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst.New Journal of Chemistry,42(2),1202-1207. |
MLA | Wang PX,et al."Transformation of CO2 into polyureas with 3-amino-1,2,4-triazole potassium as a solid base catalyst".New Journal of Chemistry 42.2(2018):1202-1207. |
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c7nj04197g.pdf(1933KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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