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Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols
DepartmentOSSO国家重点实验室
Gao Q(高倩); Xu SM(徐森苗); Xu SM(徐森苗)
The second departmentosso国家重点实验室
2018
Source PublicationOrganic and Biomolecular Chemistry
ISSN1477-0520
Volume16Issue:2Pages:208-212
Abstract

A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

Subject Area物理化学与绿色催化
DOI10.1039/c7ob02895d
Indexed BySCI
If3.423
Language英语
compositor第一作者单位
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/23762
Collection苏州研究院
羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorXu SM(徐森苗)
AffiliationState Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China
Recommended Citation
GB/T 7714
Gao Q,Xu SM,Xu SM. Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols[J]. Organic and Biomolecular Chemistry,2018,16(2):208-212.
APA Gao Q,Xu SM,&Xu SM.(2018).Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols.Organic and Biomolecular Chemistry,16(2),208-212.
MLA Gao Q,et al."Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols".Organic and Biomolecular Chemistry 16.2(2018):208-212.
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