The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries | |
Department | 固体润滑国家重点实验室 |
Wang, Jun1,3; Li, Shengli1; Zhao, Yi1; Shi, Juan1; Lv, Lili1; Wang, Huazhi1; Zhang, Zhiya1; Feng, Wangjun2 | |
2018 | |
Source Publication | RSC Advances |
ISSN | 2046-2069 |
Volume | 8Issue:12Pages:6660-6666 |
Abstract | With a high specific capacity (4200 mA h g−1), silicon based materials have become the most promising anode materials in lithium-ions batteries. However, the large volume expansion makes the capacity reduce rapidly. In this work, a periodic silicon/carbon (Si/C) multilayer thin film was synthesized by magnetron sputtering method on copper foil. The titanium (Ti) film (about 20 nm) as the transition layer was deposited on the copper foil prior to the deposition of the multilayer film. Superior electrochemical lithium storage performance was obtained by the multilayer thin film. The initial discharge and charge specific capacity of the Si (15 nm)/C (5 nm) multilayer film anode are 2640 mA h g−1 and 2560 mA h g−1 with an initial coulombic efficiency of ∼97%. The retention specific capacity is about 2300 mA h g−1 and there is ∼87% capacity retention after 200 cycles. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c7ra12027c |
Funding Organization | the Fundamental Research Funds for the Central Universities (lzujbky-2016-114;lzujbky-2016-120);the Open Project of Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University under award number LZUMMM2016012 |
Indexed By | SCI |
Language | 英语 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23724 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang, Jun |
Affiliation | 1.Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China 2.LanZhou Univ Technol, Sch Sci, Lanzhou 730000, Gansu, Peoples R China 3.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Jun,Li, Shengli,Zhao, Yi,et al. The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries[J]. RSC Advances,2018,8(12):6660-6666. |
APA | Wang, Jun.,Li, Shengli.,Zhao, Yi.,Shi, Juan.,Lv, Lili.,...&Feng, Wangjun.(2018).The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries.RSC Advances,8(12),6660-6666. |
MLA | Wang, Jun,et al."The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries".RSC Advances 8.12(2018):6660-6666. |
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c7ra12027c.pdf(844KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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