Carbon nanosphere@vanadium nitride electrode materials derived from metal-organic nanospheres self-assembled by NH4VO3, chitosan, and amphiphilic block copolymer | |
Department | 清洁能源化学与材料实验室 |
Liu, Ying1,2; Liu LY(刘灵洋)3; Tan, Yongtao1,2; Niu, Lengyuan4; Kong, Lingbin1,2; Kang, Long1,2; Ran, Fen1,2 | |
The second department | 固体润滑国家重点实验室 |
2018 | |
Source Publication | Electrochimica Acta |
ISSN | 0013-4686 |
Volume | 262Pages:66-73 |
Abstract | Supercapacitors receive numerous attentions for their high charging/discharging rate and robust cycle life, while vanadium nitride with a wide work potential window and comparable specific capacitance promotes the rapid development of negative materials for supercapacitors. In this paper, we report an in-situ preparation for nanohybrid material of carbon nanosphere@vanadium nitride (CNS@VN) derived from metal-organic framework assembled by chitosan, NH4VO3 and F127. The biomass of chitosan is used as carbon source, amphiphilic block copolymer of F127 is used as guiding agent, and the vanadium-based compound of NH4VO3 is used as precursor. The prepared CNS@VN showed an outstanding specific capacitance as high as 300.4 F/g and the estimated one for VN can reach 1241.3 F/g. Furthermore, a hybrid supercapacitor device of CNS@VN||Co3O4 is assembled by using CNS@VN and Co3O4 as the negative and positive electrode materials. The device exhibits an excellent energy density of 18.8 Wh/Kg at the power density of 800 W/kg and a prior cycle stability of 77.3% retention. This kind of hybrid material with advanced structure architecture and good electrochemical performance may open up a new design thought for negative electrode materials of supercapacitors. |
Keyword | Supercapacitor Biomass Negative Electrode Materials Vanadium Nitride |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.electacta.2017.12.194 |
Funding Organization | the National Natural Science Foundation of China (51203071;51463012;51763014);China Postdoctoral Science Foundation (2014M552509;2015T81064);Natural Science Funds of the Gansu Province (1506RJZA098);the Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology (J201402) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 低维材料与化学储能课题组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23716 |
Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室(LSL) |
Corresponding Author | Ran, Fen |
Affiliation | 1.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, PR China 2.School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou, 730050, Gansu, PR China 3.Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, PR China 4.Institute of Coordination Bond Metrology and Engineering, College of Materials Science and Engineering, China Jiliang University, Hangzhou, 310018, PR China |
Recommended Citation GB/T 7714 | Liu, Ying,Liu LY,Tan, Yongtao,et al. Carbon nanosphere@vanadium nitride electrode materials derived from metal-organic nanospheres self-assembled by NH4VO3, chitosan, and amphiphilic block copolymer[J]. Electrochimica Acta,2018,262:66-73. |
APA | Liu, Ying.,Liu LY.,Tan, Yongtao.,Niu, Lengyuan.,Kong, Lingbin.,...&Ran, Fen.(2018).Carbon nanosphere@vanadium nitride electrode materials derived from metal-organic nanospheres self-assembled by NH4VO3, chitosan, and amphiphilic block copolymer.Electrochimica Acta,262,66-73. |
MLA | Liu, Ying,et al."Carbon nanosphere@vanadium nitride electrode materials derived from metal-organic nanospheres self-assembled by NH4VO3, chitosan, and amphiphilic block copolymer".Electrochimica Acta 262(2018):66-73. |
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