FeF2/BiVO4 heterojuction photoelectrodes and evaluation of its photoelectrochemical performance for water splitting | |
Department | ERC国家工程研究中心 |
Wang, Qizhao1; Niu, Tengjiao1; Wang, Lei1; Yan, Changxin2; Huang, Jingwei1; He, Jijuan1; She, Houde1; Su, Bitao1; Bi YP(毕迎普)3; Bi YP(毕迎普) | |
The second department | osso国家重点实验室 |
2018 | |
Source Publication | Chemical Engineering Journal |
ISSN | 1385-8947 |
Volume | 337Pages:506-514 |
Abstract | A novel type of semiconductor, FeF2/BiVO4 was successfully prepared by electric deposition of precipitating FeF2 onto the surface of BiVO4 electrode so as to generate hydrogen during water splitting process. Via a list of trial catalyzed with FeF2/BiVO4 containing different contents of FeF2, the most efficient catalyst was optimised as the one with depositing FeF2 for 20 circles. Consequently, it able to produce the amount of 635.5 μmol H2 within 3 h, three times more than BiVO4 alone. The optimal photoanode of FeF2/BiVO4 exhibits a photocurrent density of 2.49 mA cm−2 at 1.23 V vs. RHE and an IPCE value of 28% at 450 nm, which are 2.26 and 3.73 times as much as pure BiVO4 photoanode, respectively. It is mainly attributed to the enhanced capacities of light absorption in the visible range and transfer of photo-generated carriers as well as separation between electrons and holes after the combination of BiVO4 and FeF2. At the same time, it offers a novel idea toward the project of solar water splitting. |
Keyword | Fef2 Nanoparticles Bivo4 Photoanode Electric Deposition P-n Type Heterostructure Water Splitting |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.cej.2017.12.126 |
Funding Organization | the National Natural Science Foundation of China (21663027;51262028;21261021);the Science and Technology Support Project of Gansu Province (1504GKCA027);the Program for the Young Innovative Talents of Longyuan, the Program for Innovative Research Team (NWNULKQN-15-2);the Undergraduate Academic Innovative Research Team of Northwest Normal University |
Indexed By | SCI |
Language | 英语 |
Funding Project | 能源与环境纳米催化材料研究组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23688 |
Collection | 精细石油化工中间体国家工程研究中心(ERC) 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Wang, Qizhao; Bi YP(毕迎普) |
Affiliation | 1.College of Chemistry and Chemical Engineering, Northwest Normal University, Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Lanzhou 730070, China 2.College of Geography and Environment Science, Northwest Normal University, Lanzhou 730070, China 3.State Key Laboratory of Oxo Synthesis & Selective Oxidation, National Engineering Research Central for Fine Petrochemical Intermediates Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China |
Recommended Citation GB/T 7714 | Wang, Qizhao,Niu, Tengjiao,Wang, Lei,et al. FeF2/BiVO4 heterojuction photoelectrodes and evaluation of its photoelectrochemical performance for water splitting[J]. Chemical Engineering Journal,2018,337:506-514. |
APA | Wang, Qizhao.,Niu, Tengjiao.,Wang, Lei.,Yan, Changxin.,Huang, Jingwei.,...&毕迎普.(2018).FeF2/BiVO4 heterojuction photoelectrodes and evaluation of its photoelectrochemical performance for water splitting.Chemical Engineering Journal,337,506-514. |
MLA | Wang, Qizhao,et al."FeF2/BiVO4 heterojuction photoelectrodes and evaluation of its photoelectrochemical performance for water splitting".Chemical Engineering Journal 337(2018):506-514. |
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