LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Anionic SO3H-functionalized ionic liquid: An efficient and recyclable catalyst for the Pechmann reaction of phenols with ethyl acetoacetate
DepartmentOSSO国家重点实验室
Song DY(宋大勇)1,2; Chen J(陈静)2; Liang YM(梁永民)1; Liang YM(梁永民)
2018
Source PublicationSynthetic Communications
ISSN0039-7911
Volume48Issue:6Pages:692-698
Abstract

This paper has reported an anionic SO3H-functionalized ionic liquid N-methylimidazolium sulfomethylsulfonate ([Hmim][HO3SCH2SO3]) for the synthesis of coumarins by Pechmann reaction. The [Hmim][HO3SCH2SO3] is easier to prepare by one-step neutralization reaction of N-methylimidazole with methanedisulfonic acid and show high catalytic performance for Pechmann reaction. Besides, the catalyst can simply be separated from the reaction mixture and recycled ten times without noticeable loss of activity.

KeywordAnionic So3h-functionalized Coumarins Ionic Liquid Pechmann Reaction
Subject Area物理化学与绿色催化
DOI10.1080/00397911.2017.1418000
Funding Organizationthe National Natural Science Foundation of China (Project No. 21473225)
Indexed BySCI
Language英语
Funding Project分子催化与技术研究组
compositor第二作者单位
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/23687
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorLiang YM(梁永民)
Affiliation1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou, Gansu, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou, Gansu, Peoples R China
Recommended Citation
GB/T 7714
Song DY,Chen J,Liang YM,et al. Anionic SO3H-functionalized ionic liquid: An efficient and recyclable catalyst for the Pechmann reaction of phenols with ethyl acetoacetate[J]. Synthetic Communications,2018,48(6):692-698.
APA Song DY,Chen J,Liang YM,&梁永民.(2018).Anionic SO3H-functionalized ionic liquid: An efficient and recyclable catalyst for the Pechmann reaction of phenols with ethyl acetoacetate.Synthetic Communications,48(6),692-698.
MLA Song DY,et al."Anionic SO3H-functionalized ionic liquid: An efficient and recyclable catalyst for the Pechmann reaction of phenols with ethyl acetoacetate".Synthetic Communications 48.6(2018):692-698.
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