Electrochemical Oxidative C-H Amination of Phenols: Access to Triarylamine Derivatives | |
Department | OSSO国家重点实验室 |
Tang, Shan1; Wang, Siyuan1; Liu, Yichang1; Cong, Hengjiang1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
2018 | |
Source Publication | Angewandte Chemie International Edition |
ISSN | 1433-7851 |
Volume | 57Issue:17Pages:4737-4741 |
Abstract | Dehydrogenative C−H/N−H cross‐coupling serves as one of the most straightforward and atom‐economical approaches for C−N bond formation. In this work, an electrochemical reaction protocol has been developed for the oxidative C−H amination of unprotected phenols under undivided electrolytic conditions. Neither metal catalysts nor chemical oxidants are needed to facilitate the dehydrogenation process. A series of triarylamine derivatives could be obtained with good functional‐group tolerance. The electrolysis is scalable and can be performed at ambient conditions. |
Keyword | Amination C-h Functionalization Cross-coupling Electrochemistry Heterocyles |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/anie.201800240 |
Funding Organization | the National Natural Science Foundation of China (21390402;21520102003);the Hubei Province Natural Science Foundation of China (2017CFA010);The Program of Introducing Talents of Discipline to Universities of China (111 Program) |
Indexed By | SCI |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23648 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Lei AW(雷爱文) |
Affiliation | 1.Wuhan Univ, Coll Chem & Mol Sci, IAS, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Tang, Shan,Wang, Siyuan,Liu, Yichang,et al. Electrochemical Oxidative C-H Amination of Phenols: Access to Triarylamine Derivatives[J]. Angewandte Chemie International Edition,2018,57(17):4737-4741. |
APA | Tang, Shan,Wang, Siyuan,Liu, Yichang,Cong, Hengjiang,Lei AW,&雷爱文.(2018).Electrochemical Oxidative C-H Amination of Phenols: Access to Triarylamine Derivatives.Angewandte Chemie International Edition,57(17),4737-4741. |
MLA | Tang, Shan,et al."Electrochemical Oxidative C-H Amination of Phenols: Access to Triarylamine Derivatives".Angewandte Chemie International Edition 57.17(2018):4737-4741. |
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