| New attempt for CO2 utilization: One-pot catalytic syntheses of methyl, ethyl and n-butyl carbamates | |
| Department | 绿色化学研究发展中心 |
Li J(李健); Qi XJ(亓秀娟) ; Wang LG(王利国); He YD(何昱德); Deng YQ(邓友全)
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| 2011 | |
| Source Publication | Catalysis Communications
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| ISSN | 1566-7367 |
| Volume | 12Pages:1224-1227 |
| Abstract | The direct production of methyl, ethyl and n-butyl carbamates (MC, EC and BC) from NH3, CO2 and alcohols could efficiently be catalyzed by V2O5, and ca. 11–25% yields with 98% selectivity for alkyl carbamates could be obtained. The catalyst could be recycled six times without obvious decrease in catalytic activity. XRD and XPS analysis showed that in-situ produced (NH4)2V3O8 was the catalytically active species. |
| Keyword | Carbon Dioxide Vanadium(v)-oxide Catalyst Fixation Alkyl Carbamates |
| Subject Area | 物理化学 |
| Funding Organization | supercomputing center;Computer Network Information Center (CNIC);Chinese Academy of Sciences (CAS) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2362 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Li J,Qi XJ,Wang LG,et al. New attempt for CO2 utilization: One-pot catalytic syntheses of methyl, ethyl and n-butyl carbamates[J]. Catalysis Communications,2011,12:1224-1227. |
| APA | 李健,亓秀娟,王利国,何昱德,&邓友全.(2011).New attempt for CO2 utilization: One-pot catalytic syntheses of methyl, ethyl and n-butyl carbamates.Catalysis Communications,12,1224-1227. |
| MLA | 李健,et al."New attempt for CO2 utilization: One-pot catalytic syntheses of methyl, ethyl and n-butyl carbamates".Catalysis Communications 12(2011):1224-1227. |
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| Catalysis Communicat（554KB） | 开放获取 | License | View Application Full Text | |||
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