HZSM-5 supported silica-zirconia and its application in one-step synthesis of methyl isobutyl ketone | |
Department | 羰基合成与选择氧化国家重点实验室 ; 绿色化学研究发展中心 |
Liu YX(刘艳侠); Sun KP(孙鲲鹏); Xu XL(徐贤伦); Wang XL(王晓来) | |
2010 | |
Source Publication | Catal. Commun. |
ISSN | 1566-7367 |
Volume | 11Pages:322-325 |
Abstract | In order to adjust the acidity and texture property of HZSM-5, SiO2–ZrO2 was introduced via a modified sol–gel method. Pd-loaded catalyst was prepared and its catalytic activity was tested in one-step synthesis of MIBK. The catalyst exhibited a significant activity of acetone conversion up to 33.4% and MIBK selectivity up to 88.1% under atmospheric pressure. The acidity and textural properties of support material, as well as palladium dispersion of Pd-loaded catalyst were characterized. The results indicated that the proper acid strength and textural property of the support, together with the high dispersion of palladium resulted in good catalytic performance. |
Keyword | Condensation Methyl Isobutyl Ketone Bifunctional Catalyst Hzsm-5 Sio2–zro2 |
Subject Area | 仿生与生物催化 |
Indexed By | SCI |
Language | 英语 |
Funding Project | 多相选择氧化研究组 ; 精细石油化工催化课题组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2323 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 绿色化学研究发展中心 |
Corresponding Author | Xu XL(徐贤伦); Wang XL(王晓来) |
Recommended Citation GB/T 7714 | Liu YX,Sun KP,Xu XL,et al. HZSM-5 supported silica-zirconia and its application in one-step synthesis of methyl isobutyl ketone[J]. Catal. Commun.,2010,11:322-325. |
APA | 刘艳侠,孙鲲鹏,徐贤伦,&王晓来.(2010).HZSM-5 supported silica-zirconia and its application in one-step synthesis of methyl isobutyl ketone.Catal. Commun.,11,322-325. |
MLA | 刘艳侠,et al."HZSM-5 supported silica-zirconia and its application in one-step synthesis of methyl isobutyl ketone".Catal. Commun. 11(2010):322-325. |
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