| Ultra-chemoselective hydrogenation of chloronitrobenzenes to chloroanilines over HCl-acidified attapulgite-supported platinum catalyst with high activity | |
| Department | 绿色化学研究发展中心 ; 羰基合成与选择氧化国家重点实验室 |
Ma HW(马好文); Sun KP(孙鲲鹏) ; Li YW(李永文); Xu XL(徐贤伦)
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| 2009 | |
| Source Publication | Catalysis Communications
 |
| ISSN | 1566-7367 |
| Volume | 10Pages:1363-1366 |
| Abstract | HCl-acidified attapulgite-supported platinum nanocomposite catalyst was prepared by a simple method for the selective hydrogenation of hloronitrobenzenes to the corresponding chloroanilines under rela-tively mild conditions. The nanocomposite catalyst exhibited excellent catalytic activity and selectivity for the selective hydrogenation of p-chloronitrobenzene, m-chloronitrobenzene and o-chloronitroben-zene. The selectivity to chloroanilines could be up to 100% at complete conversion of chloronitrobenzenes under 2.0 MPa and 50 C. The catalyst structure was characterized by TEM, XPS and BET, and both the mechanism of high activity and the reason for the deactivation of the catalyst were discussed. |
| Keyword | Selective Hydrogenation Platinum Attapulgite Chloronitrobenzenes Dechlorination |
| Subject Area | 物理化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 精细石油化工催化课题组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2309 |
| Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xu XL(徐贤伦) |
| Recommended Citation GB/T 7714 | Ma HW,Sun KP,Li YW,et al. Ultra-chemoselective hydrogenation of chloronitrobenzenes to chloroanilines over HCl-acidified attapulgite-supported platinum catalyst with high activity[J]. Catalysis Communications,2009,10:1363-1366. |
| APA | 马好文,孙鲲鹏,李永文,&徐贤伦.(2009).Ultra-chemoselective hydrogenation of chloronitrobenzenes to chloroanilines over HCl-acidified attapulgite-supported platinum catalyst with high activity.Catalysis Communications,10,1363-1366. |
| MLA | 马好文,et al."Ultra-chemoselective hydrogenation of chloronitrobenzenes to chloroanilines over HCl-acidified attapulgite-supported platinum catalyst with high activity".Catalysis Communications 10(2009):1363-1366. |
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| Catalysis Communicat（202KB） | 开放获取 | License | View Application Full Text | |||
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