| Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst | |
| Department | 绿色化学研究发展中心 ; 羰基合成与选择氧化国家重点实验室 |
Guo XG(郭晓光); Shang JP(尚建鹏) ; Ma XY(马祥元); Li J(李健); Zhang HZ(张宏哲); Cui XJ(崔新江); Shi F(石峰); Deng YQ(邓友全)
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| 2009 | |
| Source Publication | Catalysis Communications
 |
| ISSN | 1566-7367 |
| Volume | 10Pages:1248-1251 |
| Abstract | A series of catalysts (e.g. FeCl3, Zn(OAc)2, Pb(NO3)2, etc.) were tested for the trans-esterification reaction of 1,6-hexamethylenediamine (HDA) with methyl carbamate (MC), ethyl carbamate (EC), and butyl car-bamate (BC) to afford dialkyl hexamethylene-1,6-dicarbamate (AHDC). By applying the optimized condi-tion, 100% conversion of HDA and 93% yield to diethyl hexamethylene-1,6-dicarbamate (EHDC) could be obtained using FeCl3 as catalyst. The desired products could be precipitated by adding water into the resulting mixture, and the activity of recovered catalyst could be maintained. |
| Keyword | Non-phosgene Carbamate Carbonylation Isocyanate 1 6-hexamethylenediamine |
| Subject Area | 物理化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2296 |
| Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Guo XG,Shang JP,Ma XY,et al. Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst[J]. Catalysis Communications,2009,10:1248-1251. |
| APA | 郭晓光.,尚建鹏.,马祥元.,李健.,张宏哲.,...&邓友全.(2009).Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst.Catalysis Communications,10,1248-1251. |
| MLA | 郭晓光,et al."Synthesis of dialkyl hexamethylene-1,6-dicarbamate from 1,6-hexamethylenediamine and alkyl carbamate over FeCl3 as catalyst".Catalysis Communications 10(2009):1248-1251. |
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