| Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Xia YN(夏娅娜) ; Wu B(吴彪); Li SG(李少光); Yang ZW(杨再文); Liu YY(刘艳艳); Yang XJ(杨晓娟)
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| 2010 | |
| Source Publication | Supramolecular Chemistry
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| ISSN | 1061-0278 |
| Volume | 22Issue:5Pages:318-324 |
| Abstract | A flexible bis(pyridylcarbamate) receptor, 3-pyridyl-carbamic-acid-oxydi-1,2-ethanediylester (L2) and the anion complexes (1–3) of the doubly protonated ligand ([L2H2]2þ) with ClO-4 , SO-24 and Cl2 are reported. The binding modes of [L2H2]2þ with the anions in 1–3 in the solid state are established by X-ray single crystal diffraction. Compounds 1 and 3 feature intriguing anionic polymer fashions. In compound 1, two zigzag perchlorate–water chains are encapsulated in the 1D channel constructed by 2þ2 (2[L2H2]2þ þ 2ClO-4 ) hydrogen-bonded macrocycles, while in 3 the chloride ions are trapped on the wall of the hydrogen-bonded 1D channel formed by two U-shaped ligands. For compound 2, the packing diagram displays a corrugated layer structure, with the sulphate ions and the water molecules located between the layers. Receptor L2 crystallises with perchlorate from the acid mixture HClO4, H2SO4 and HCl. |
| Keyword | Anion Receptor Bis(Pyridylcarbamate) Hydrogen-bonded Macrocycle |
| Subject Area | 金属有机功能材料 |
| Funding Organization | the National Natural Science Foundation of China (Grant No. 20872149);the “Bairen Jihua” project of Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2285 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Xia YN,Wu B,Li SG,et al. Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer[J]. Supramolecular Chemistry,2010,22(5):318-324. |
| APA | 夏娅娜,吴彪,李少光,杨再文,刘艳艳,&杨晓娟.(2010).Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer.Supramolecular Chemistry,22(5),318-324. |
| MLA | 夏娅娜,et al."Anion binding of a bis(pyridylcarbamate) receptor bearing a diethylene glycol spacer".Supramolecular Chemistry 22.5(2010):318-324. |
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