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Morphology control of polyaniline by dopant grown on hollow carbon fibers as high-performance supercapacitor electrodes
Department环境材料与生态化学研究发展中心
Xu WB(许卫兵)1,2; Mu B(牟斌)1; Wang AQ(王爱勤)1; Mou B(牟斌); Wang AQ(王爱勤)
The second department固体润滑国家重点实验室
2017
Source PublicationCellulose
ISSN0969-0239
Volume24Issue:12Pages:5579-5592
Abstract

The various morphologies of polyaniline are grown on carbon fibers derived from natural hollow cellulose by in situ polymerization of aniline. The morphologies of nanofibers, pyramid-like, nanorods and nanowires can be facilely controlled by the doping of hydrochloric acid, sulfuric acid, perchloric acid, phosphoric acid and p-toluenesulfonic acid, respectively. The perchloric acid doped composite shown the maximum specific capacitance of 580 F g−1 at 1.0 A g−1. Remarkably, the all solid-state supercapacitors based on this sample deliver a maximum energy density of 13.3 Wh kg−1. The excellent performance is attributed to the unique morphology and hollow structure of the conductive substrate, which can drastically facilitate the ion diffusion and improve the utilization of the electroactive.

KeywordKapok Fiber Hollow Carbon Fibers Polyaniline Morphology Control Supercapacitors
Subject Area环境材料与生态化学
DOI10.1007/s10570-017-1505-5
Funding Organizationthe National Natural Science Foundation of China (No. 51,303,190)
Indexed BySCI
If3.417
Language英语
Funding Project功能复合材料研究组
compositor第一作者单位
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/22790
Collection环境材料与生态化学研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorMou B(牟斌); Wang AQ(王爱勤)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xu WB,Mu B,Wang AQ,et al. Morphology control of polyaniline by dopant grown on hollow carbon fibers as high-performance supercapacitor electrodes[J]. Cellulose,2017,24(12):5579-5592.
APA Xu WB,Mu B,Wang AQ,牟斌,&王爱勤.(2017).Morphology control of polyaniline by dopant grown on hollow carbon fibers as high-performance supercapacitor electrodes.Cellulose,24(12),5579-5592.
MLA Xu WB,et al."Morphology control of polyaniline by dopant grown on hollow carbon fibers as high-performance supercapacitor electrodes".Cellulose 24.12(2017):5579-5592.
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