Spontaneous Growth of 3D Framework Carbon from Sodium Citrate for High Energy- and Power-Density and Long-Life Sodium-Ion Hybrid Capacitors | |
Department | 清洁能源化学与材料实验室 |
Yang BJ(杨兵军)#1; Chen JT(陈江涛)#1; Lei SL(类淑来)1; Guo RS(郭瑞生)1; Li HX(李红霞)1,2; Shi SQ(史思琪)3; Yan XB(阎兴斌)1; Yan XB(阎兴斌) | |
The second department | 低维材料与化学储能研究组 |
2018 | |
Source Publication | Advcaned Energy Materials |
ISSN | 1614-6832 |
Volume | 8Issue:10Pages:1702409(1-11) |
Abstract | Carbon sheets with 3D architectures, large graphitic interlayer spacing, and high electrical conductivity are highly expected to be an ideal anode material for sodium-ion hybrid capacitors (SIHCs). Pursuing a simple synthesis methodology and advancing it from the laboratory to industry is of great importance. In this study, a new approach is presented to prepare 3D framework carbon (3DFC) with the above integrated advantages by a direct calcination of sodium citrate without aid of any additional carbon source, template, or catalyst. The first-principle calculations verify that the large interlayer spacing and the curvature structure of 3DFC facilitate the sodium ion insertion/extraction. As a consequence, the optimal 3DFC sample exhibits high reversible capacity as well as excellent rate and cycling performance. On this basis, a dual-carbon SIHC is fabricated by employing 3DFC as battery-type anode and 3DFC-derived nanoporous carbon as capacitor-type cathode. It is able to deliver high energy- and power-density feature as well as outstanding long-term cycling stability in the potential range of 0–4.0 V. This study may open an avenue for developing high-performance carbon electrode materials and pushes the practical applications of SIHCs a decisive step forward. |
Keyword | 3d Framework Carbon Sheets Dual-carbon Batteries Hybrid Capacitors Sodium Ion Batteries |
Subject Area | 材料科学与物理化学 |
DOI | 10.1002/aenm.201702409 |
Funding Organization | the National Nature Science Foundations of China (Grant No. 21573265 ; 21673263 ; 51501208) |
Indexed By | SCI |
If | 21.875 |
Language | 英语 |
Funding Project | 低维材料与化学储能研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22782 |
Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室(LSL) |
Corresponding Author | Yan XB(阎兴斌) |
Affiliation | 1.Laboratory of Clean Energy Chemistry and Materials State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000, P. R. China 2.University of Chinese Academy of Sciences Beijing 100039, P. R. China 3.School of Materials Science and Engineering Shanghai University Shanghai 200444, P. R. China |
Recommended Citation GB/T 7714 | Yang BJ,Chen JT,Lei SL,et al. Spontaneous Growth of 3D Framework Carbon from Sodium Citrate for High Energy- and Power-Density and Long-Life Sodium-Ion Hybrid Capacitors[J]. Advcaned Energy Materials,2018,8(10):1702409(1-11). |
APA | Yang BJ.,Chen JT.,Lei SL.,Guo RS.,Li HX.,...&Yan XB.(2018).Spontaneous Growth of 3D Framework Carbon from Sodium Citrate for High Energy- and Power-Density and Long-Life Sodium-Ion Hybrid Capacitors.Advcaned Energy Materials,8(10),1702409(1-11). |
MLA | Yang BJ,et al."Spontaneous Growth of 3D Framework Carbon from Sodium Citrate for High Energy- and Power-Density and Long-Life Sodium-Ion Hybrid Capacitors".Advcaned Energy Materials 8.10(2018):1702409(1-11). |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
aem.pdf(4541KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment