LICP OpenIR  > 环境材料与生态化学研究发展中心
Preparation, swelling behaviors and application of polyacrylamide/attapulgite superabsorbent composites
Department环境材料与生态化学研究发展中心
Zhang JP(张俊平); Liu RF(刘瑞凤); Li A(李安); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2006
Source PublicationPolymers for Advanced Technologies
ISSN1042-7147
Volume17Pages:12-19
AbstractA series of superabsorbent composites, polyacrylamide/attapulgite (PAMA), were prepared from acrylamide (AM) and attapulgite micropowder in aqueous solution, using N,N′-methylenebisacrylamide (MBA) as a crosslinker and ammonium persulfate (APS) as an initiator and then saponified with sodium hydroxide solution. This paper focuses on swelling behaviors of the PAMA superabsorbent composites in various saline solutions. The results indicate that saline solutions can weaken the swelling abilities of the PAMA compsites greatly. Water absorbency of the PAMA composites with 20 and 40?wt% attapulgite in aqueous chloride salt solutions has the following order: Li+?=?Na+?=?K+, Mg2+?>?Ca2+?=?Ba2+ all through the range of concentration investigated. However, swelling properties of the composites are complicated in CuCl2(aq), AlCl3(aq) and FeCl3(aq) solutions and are related to saline solutions concentration. The deswelling behavior of PAMA composites is more obvious in univalent chloride salt solutions than in divalent and trivalent ones. The influence of kind and valence of anions on swelling ability of the composites is limited and almost the same. Moreover, reswelling capability, practical water retention ability in sand soil of the composites and the effect of pH on water absorbency of the PAMA composites were investigated. The PAMA composite shows good water retention and reswelling ability in sand soil, and may be used as a recyclable water-managing material for the renewal of arid and desert environment.
KeywordSuperabsorbent Composites Water Absorbency Swelling Recycling
Subject Area功能高分子
Funding Organizationthe Western Action Project of CAS(No. KGCXZ-SW-502);“863” major project of the Ministry of Science and Technology, P. R. China (No. 2005AA2Z4030)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Citation statistics
Cited Times:52[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/225
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Zhang JP,Liu RF,Li A,et al. Preparation, swelling behaviors and application of polyacrylamide/attapulgite superabsorbent composites[J]. Polymers for Advanced Technologies,2006,17:12-19.
APA 张俊平,刘瑞凤,李安,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2006).Preparation, swelling behaviors and application of polyacrylamide/attapulgite superabsorbent composites.Polymers for Advanced Technologies,17,12-19.
MLA 张俊平,et al."Preparation, swelling behaviors and application of polyacrylamide/attapulgite superabsorbent composites".Polymers for Advanced Technologies 17(2006):12-19.
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