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Graphene oxide-templated growth of MOFs with enhanced lithium-storage properties
Department固体润滑国家重点实验室
He SH(何淑花)1,2; Li ZP(李章朋)1; Ma LM(马立民)1; Wang JQ(王金清)1; Yang SR(杨生荣)1; Wang JQ(王金清); Yang SR(杨生荣)
2017
Source PublicationNew Journal of Chemistry
ISSN1144-0546
Volume41Issue:23Pages:14209-14216
Abstract

Herein, Mn-MOF/RGOn composites have been successfully synthesized using terephthalic acid non-covalent functionalized graphene oxide (GO) sheets acting as efficient nucleation sites and structure-directing templates to direct the growth of MOFs. The electrochemical performance of the Mn-MOF/RGOn composite electrode was much better than that of the pristine Mn-MOF when used as a candidate anode material for lithium-ion batteries due to the synergetic advantages of RGO and Mn-MOF, improved electrical conductivity, and mechanical flexibility of Mn-MOF. Especially, the Mn-MOF/RGO10 composite electrode maintains a reversible discharge capacity of 715 mA h g−1 with a capacity retention of 98% after 100 cycles at 100 mA g−1 and also exhibits a high discharge capacity of 485 mA h g−1 at 300 mA g−1, 432 mA h g−1 at 500 mA g−1 while still maintaining 348 mA h g−1 at 1000 mA g−1 after 500 cycles, which is greatly higher as compared to that of the pure Mn-MOF material as expected.

Subject Area材料科学与物理化学
DOI10.1039/c7nj02846f
Funding Organizationthe National Natural Science Foundation of China (No. 51502306;51675514)
Indexed BySCI
If3.269
Language英语
Funding Project聚合物摩擦学研究组
compositor第一作者单位
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/22594
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang JQ(王金清); Yang SR(杨生荣)
Affiliation1.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
2.University of Chinese Academy of Sciences, Beijing 100080, P. R. China
Recommended Citation
GB/T 7714
He SH,Li ZP,Ma LM,et al. Graphene oxide-templated growth of MOFs with enhanced lithium-storage properties[J]. New Journal of Chemistry,2017,41(23):14209-14216.
APA He SH.,Li ZP.,Ma LM.,Wang JQ.,Yang SR.,...&杨生荣.(2017).Graphene oxide-templated growth of MOFs with enhanced lithium-storage properties.New Journal of Chemistry,41(23),14209-14216.
MLA He SH,et al."Graphene oxide-templated growth of MOFs with enhanced lithium-storage properties".New Journal of Chemistry 41.23(2017):14209-14216.
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