Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol | |
Department | OSSO国家重点实验室 |
Liu, Hailong1; Huang ZW(黄志威)1; Kang HX(康海笑)1; Li XM(李雪梅)1; Xia CG(夏春谷)1; Chen J(陈静)1; Liu, Haichao2 | |
2018 | |
Source Publication | Applied Catalysis B: Environmental |
ISSN | 0926-3373 |
Volume | 220Issue:无Pages:251-263 |
Abstract | The selective hydrogenolysis of biomass-derived xylitol to ethylene glycol and propylene glycol was carried out over non-noble Ni-decorated Cu-SiO2 nanocatalysts with a wide range of Cu/Ni mass ratios and metal loadings in the presence of Ca(OH)2. The NiCu-SiO2 bimetallic catalysts showed much superior activities and selectivities to the target glycols relative to the monometallic Cu-SiO2 and Ni-SiO2 catalysts. Among them, 10Ni80Cu-SiO2 catalyst (10/80 refers to the mass ratio of NiO and CuO) prepared by co-precipitation-gel method presented the highest activity and target glycols selectivity, and up to 81.0% combined glycol yield was attained at 473 K and 8 MPa H2. Moreover, this catalyst exhibited greatly enhanced stability in repeated runs. Characterization of these catalysts by XRD, XPS, BET, N2O-chemisorption, H2-TPR and TEM showed that the decoration of suitable amount of Ni into Cu-SiO2 catalysts had favorable effects on Cu dispersion, catalyst reducibility and the formation of highly active Ni surface-enriched Cu-Ni alloy sites. The notably enhanced performances of the NiCu-SiO2 bimetallic catalysts could be ascribed to their significantly promoted C-OH dehydrogenation and C=O hydrogenation activities and high resistance to sintering of the active sites, imposed by the structural and electronic effects of Ni. Clearly, these findings provide useful guidance for the design of more efficient and stable non-noble bimetallic nanocatalysts for upgrading biomass-derived platform compounds particularly via hydrogenation/hydrogenolysis reactions. |
Keyword | Biomass-derived Xylitol Ethylene Glycol Propylene Glycol Selective Hydrogenolysis Nicu Bimetallic Catalyst |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.apcatb.2017.08.022 |
Funding Organization | the National Natural Science Foundation of China (Grant No. 21473224 ; 21203221) the Suzhou Science and Technology Development Plan (SYG201626) ; Zhiwei Huang acknowledges the support from China Scholarship Council for the Visiting Scholars Program (File No. 201604910003) ; the Youth Innovation Promotion Association, CAS |
Indexed By | SCI |
If | 11.7 |
Language | 英语 |
Funding Project | 分子催化与技术研究组 ; 均相催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22521 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Huang ZW(黄志威); Chen J(陈静) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
Recommended Citation GB/T 7714 | Liu, Hailong,Huang ZW,Kang HX,et al. Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol[J]. Applied Catalysis B: Environmental,2018,220(无):251-263. |
APA | Liu, Hailong.,Huang ZW.,Kang HX.,Li XM.,Xia CG.,...&Liu, Haichao.(2018).Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol.Applied Catalysis B: Environmental,220(无),251-263. |
MLA | Liu, Hailong,et al."Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol".Applied Catalysis B: Environmental 220.无(2018):251-263. |
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