Asymmetric Synthesis of Glutamic Acid Derivatives by Silver-Catalyzed Conjugate Addition-Elimination Reactions | |
Department | 苏州研究院 |
Yuan, Yang1; Yu, Bo1; Bo XF(柏惺峰)1; Xu, Zheng1; Zheng ZJ(郑战江)1; Cui, Yu-Ming1; Cao, Jian1; Xu LW(徐利文)1,2; Xu LW(徐利文); Zheng ZJ(郑战江) | |
The second department | osso国家重点实验室 |
2017 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 19Issue:18Pages:4896-4899 |
Abstract | The enantioselective construction of a family of chiral glycine-derived aldimino esters is described. The asymmetric tandem conjugate addition–elimination procedure is characterized by its exceptional mild reaction conditions and features with an exquisite enantioselectivity profile using commercially available silver/DTBM-SegPhos catalyst, allowing for the facile preparation of a variety of substituted and chiral glutamic acid derivatives (up to 99% ee) bearing Schiff base in a straightforward manner. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acs.orglett.7b02378 |
Funding Organization | the National Natural Science Foundation of China (Nos. 21472031;21503060;21702211;21773051);Zhejiang Provincial Natural Science Foundation of China (LR14B030001;LY17E030003;LY17B030005) |
Indexed By | SCI |
If | 6.579 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22514 |
Collection | 苏州研究院 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Xu LW(徐利文); Zheng ZJ(郑战江) |
Affiliation | 1.Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, P. R. China 2.Suzhou Research Institute and State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China |
Recommended Citation GB/T 7714 | Yuan, Yang,Yu, Bo,Bo XF,et al. Asymmetric Synthesis of Glutamic Acid Derivatives by Silver-Catalyzed Conjugate Addition-Elimination Reactions[J]. Organic Letters,2017,19(18):4896-4899. |
APA | Yuan, Yang.,Yu, Bo.,Bo XF.,Xu, Zheng.,Zheng ZJ.,...&郑战江.(2017).Asymmetric Synthesis of Glutamic Acid Derivatives by Silver-Catalyzed Conjugate Addition-Elimination Reactions.Organic Letters,19(18),4896-4899. |
MLA | Yuan, Yang,et al."Asymmetric Synthesis of Glutamic Acid Derivatives by Silver-Catalyzed Conjugate Addition-Elimination Reactions".Organic Letters 19.18(2017):4896-4899. |
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