Durable superamphiphobic coatings repelling both cool and hot liquids based on carbon nanotubes | |
Department | 甘肃省黏土矿物应用重点实验室 |
Zhai, Naihua1; Fan L(范玲)2; Li LX(李凌霄)2; Zhang JP(张俊平)2; Zhang JP(张俊平) | |
The second department | 环境材料与生态化学研究发展中心 |
2017 | |
Source Publication | Journal of Colloid and Interface Science |
ISSN | 0021-9797 |
Volume | 505Pages:622-630 |
Abstract | Superamphiphobic coatings have wide potential applications in many fields, however, preparation of superamphiphobic coatings with low sliding angles and high durability is very challenging. Here, we report a facile spray-coating method for the preparation of durable superamphiphobic coatings repelling both cool and hot liquids from polyperfluoroalkylsilane-modified multiwalled carbon nanotubes (MWCNTs@fluoroPOS). The MWCNTs@fluoroPOS suspensions were preparation by hydrolytic condensation of 1H,1H,2H,2H-perfluorodecyltrichlorosilane (PFDTES) and tetraethoxysilane (TEOS) on the surface of MWCNTs. The suspensions and the superamphiphobic coatings were characterized using a variety of analytical techniques such as scanning electron microscopy, transmitting electron microscopy and X-ray photoelectron spectroscopy. The effects of the diameter of MWCNTs, and the concentrations of MWCNTs, TEOS and PFDTES on wettability and microstructure of the coatings were also investigated. The coatings show high contact angles and low sliding angles for water and organic liquids of low surface tension such as n-hexadecane, toluene and n-decane. The coatings even exhibit excellent superamphiphobicity for hot water and hot organic liquids up to 80 ℃, which is seldom achieved according to the previous literatures. Moreover, the coatings feature high mechanical, chemical and environmental durability, and are applicable onto various substrates. The simple method, the high superamphiphobicity to both cool and hot liquids, and the excellent durability of the coatings have paved the way for their practical applications in various fields, e.g., anti-icing, anti-oil climbing and oil transportation, etc. |
Keyword | Superoleophobic Silanes Wettability Carbon Nanotubes Sliding Angle |
Subject Area | 环境材料与生态化学 |
DOI | 10.1016/j.jcis.2017.06.050 |
Funding Organization | the ‘‘Hundred Talents Program” of the Chinese Academy of Sciences |
Indexed By | SCI |
If | 4.233 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22481 |
Collection | 甘肃省黏土矿物应用研究重点实验室 环境材料与生态化学研究发展中心 |
Corresponding Author | Zhang JP(张俊平) |
Affiliation | 1.College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, 266109 Qingdao, PR China 2.Key Laboratory of Clay Mineral Applied Research of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000 Lanzhou, PR China |
Recommended Citation GB/T 7714 | Zhai, Naihua,Fan L,Li LX,et al. Durable superamphiphobic coatings repelling both cool and hot liquids based on carbon nanotubes[J]. Journal of Colloid and Interface Science,2017,505:622-630. |
APA | Zhai, Naihua,Fan L,Li LX,Zhang JP,&张俊平.(2017).Durable superamphiphobic coatings repelling both cool and hot liquids based on carbon nanotubes.Journal of Colloid and Interface Science,505,622-630. |
MLA | Zhai, Naihua,et al."Durable superamphiphobic coatings repelling both cool and hot liquids based on carbon nanotubes".Journal of Colloid and Interface Science 505(2017):622-630. |
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1-s2.0-S002197971730(2210KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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