Designing non-noble/semiconductor Bi/BiVO4 photoelectrode for the enhanced photoelectrochemical performance | |
Department | ERC国家工程研究中心 |
Wang, Qizhao1; He, Jijuan1; Shi, Yanbiao1; Zhang, Shuling1; Niu, Tengjiao1; She, Houde1; Bi YP(毕迎普)2; Bi YP(毕迎普) | |
The second department | osso国家重点实验室 |
2017 | |
Source Publication | Chemical Engineering Journal |
ISSN | 1385-8947 |
Volume | 326Pages:411-418 |
Abstract | Bi/BiVO4 photoelectrode was prepared on FTO glass by the combination of electrochemical deposition, heating treatment and photo-assisted reduction method at room temperature. All of the samples were characterized by X-ray diffraction spectrum (XRD), scanning electron microscope (SEM) and UV-vis diffuse reflectance spectrum (DRS), respectively. The results indicated that metallic Bi particles were well deposited on porous BiVO4 film during the deposition process of photo-assisted reduction, resulting in a greatly broadened visible light absorption edge than that of BiVO4 alone. The optimized photoelectrochemical (PEC) performance of Bi/BiVO4-60 was further verified by linear scan voltammetry (LSV), current-time (I-t) and incident photon-to-current efficiency (IPCE), respectively. It was conjectured the broadened visible light response range of Bi/BiVO4 PEC system and the increased counteraction against positive charge both were caused by the electron transferred from BiVO4 to Bi, and thus effectively facilitated the separation and transfer of photo-generated carriers and thus promote the PEC water splitting performance. |
Keyword | Bi/bivo4 Photoelectrodes Photoelectrochemical Performance Hydrogen Evolution |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.cej.2017.05.171 |
Funding Organization | the National Natural Science Foundation of China (21663027;51262028;21261021);the Science and Technology Support Project of Gansu Province (1504GKCA027);the Program for the Young Innovative Talents of Longyuan;the Program for Innovative Research Team (NWNULKQN-15-2);the Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (LZJ1502);the Undergraduate Academic Innovative Research Team of Northwest Normal University |
Indexed By | SCI |
If | 6.216 |
Language | 英语 |
Funding Project | 能源与环境纳米催化材料研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22210 |
Collection | 精细石油化工中间体国家工程研究中心(ERC) 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Wang, Qizhao; Bi YP(毕迎普) |
Affiliation | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecoenvironm Related Polymer Mat, Minist Educ China, Lanzhou 730070, Gansu, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Qizhao,He, Jijuan,Shi, Yanbiao,et al. Designing non-noble/semiconductor Bi/BiVO4 photoelectrode for the enhanced photoelectrochemical performance[J]. Chemical Engineering Journal,2017,326:411-418. |
APA | Wang, Qizhao.,He, Jijuan.,Shi, Yanbiao.,Zhang, Shuling.,Niu, Tengjiao.,...&毕迎普.(2017).Designing non-noble/semiconductor Bi/BiVO4 photoelectrode for the enhanced photoelectrochemical performance.Chemical Engineering Journal,326,411-418. |
MLA | Wang, Qizhao,et al."Designing non-noble/semiconductor Bi/BiVO4 photoelectrode for the enhanced photoelectrochemical performance".Chemical Engineering Journal 326(2017):411-418. |
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