Charge-Transfer Complex Promoted C-N Bond Activation for Ni-Catalyzed Carbonylation | |
Department | OSSO国家重点实验室 |
Yu H(余慧)1,3; Gao, Bao2; Hu B(胡斌)1; Huang HM(黄汉民)1,2; Hu B(胡斌); Huang HM(黄汉民) | |
2017 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 19Issue:13Pages:3520-3523 |
Abstract | A new strategy was developed for activation of C–N bond via formation of an amine–I2 charge-transfer complex, which facilitates the inert C–N bond activation via oxidative addition with Ni(0). This strategy has been successfully applied in the Ni-catalyzed carbonylation of benzylamines via direct insertion of CO into the C–N bond, which provided a straightforward and rapid approach to arylacetamides in the presence of catalytic amounts of I2 and Ni catalyst. Mechanistic studies suggested that a benzyl radical generated via the oxidative addition was involved in the present reaction. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acs.orglett.7b01488 |
Funding Organization | the National Natural Science Foundation of China (21672199);the CAS Interdisciplinary Innovation Team;the Anhui Provincial Natural Science Foundation (1708085MB28) |
Indexed By | SCI |
If | 6.579 |
Language | 英语 |
Funding Project | 羰基金属功能材料研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22192 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Hu B(胡斌); Huang HM(黄汉民) |
Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China 2.Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China 3.University of Chinese Academy of Sciences, Beijing 100049, P. R. China |
Recommended Citation GB/T 7714 | Yu H,Gao, Bao,Hu B,et al. Charge-Transfer Complex Promoted C-N Bond Activation for Ni-Catalyzed Carbonylation[J]. Organic Letters,2017,19(13):3520-3523. |
APA | Yu H,Gao, Bao,Hu B,Huang HM,胡斌,&黄汉民.(2017).Charge-Transfer Complex Promoted C-N Bond Activation for Ni-Catalyzed Carbonylation.Organic Letters,19(13),3520-3523. |
MLA | Yu H,et al."Charge-Transfer Complex Promoted C-N Bond Activation for Ni-Catalyzed Carbonylation".Organic Letters 19.13(2017):3520-3523. |
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