LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Peculiar synergetic effect of MoS2 quantum dots and graphene on Metal-Organic Frameworks for photocatalytic hydrogen evolution
DepartmentERC国家工程研究中心
Hao, Xuqiang1,3; Jin ZL(靳治良)1; Yang, Hao1; Lu GX(吕功煊)2; Bi YP(毕迎普)2; Jin ZL(靳治良)
The second departmenterc国家工程研究中心
2017
Source PublicationApplied Catalysis B: Environmental
ISSN0926-3373
Volume210Pages:45-56
Abstract

Special enhanced synergetic effect of MoS2 quantum dots (MoS2 QDs) and graphene on metal-organic frameworks for photocatalytic hydrogen evolution is obtained here. The photocatalytic activity of H2 evolution reach 186.37 mu mol over the EY-sensitized 5 rift% MoS2 QDs/UiO-66-NH2/G irradiated under visible light irradiation (λ ≥ 420nm) in the first 3 h, and the apparent quantum efficiency (AQE) is 40.5% at 430 nm. The synergistic effect between MoS2 QDs and graphene together with UiO-66-NH2 is corroborated by photo-luminescence spectra, electro-chemical and photo-electro-chemical experiments. It demonstrate that the charge separation and the electrons transfer are more efficient with the aid of the MoS2 QDs and graphene. MoS2 QDs might be a potential photocatalyst for design new type of catalysts in photocatalysis proton reduction.

KeywordMos2 Qds Metal-organic Frameworks Graphene Photocatalytic Hydrogen Evolution
Subject Area物理化学与绿色催化
DOI10.1016/j.apcatb.2017.03.057
Funding Organizationthe Chinese National Natural Science Foundation (21603274;21263001;41663012;21433007)
Indexed BySCI
If9.446
Language英语
Funding Project环境催化与氢能研究组;能源与环境纳米催化材料研究组
compositor第二作者单位
Citation statistics
Cited Times:265[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/22175
Collection羰基合成与选择氧化国家重点实验室(OSSO)
精细石油化工中间体国家工程研究中心(ERC)
Corresponding AuthorJin ZL(靳治良)
Affiliation1.Beifang Univ Nationalities, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
3.Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China
Recommended Citation
GB/T 7714
Hao, Xuqiang,Jin ZL,Yang, Hao,et al. Peculiar synergetic effect of MoS2 quantum dots and graphene on Metal-Organic Frameworks for photocatalytic hydrogen evolution[J]. Applied Catalysis B: Environmental,2017,210:45-56.
APA Hao, Xuqiang,Jin ZL,Yang, Hao,Lu GX,Bi YP,&靳治良.(2017).Peculiar synergetic effect of MoS2 quantum dots and graphene on Metal-Organic Frameworks for photocatalytic hydrogen evolution.Applied Catalysis B: Environmental,210,45-56.
MLA Hao, Xuqiang,et al."Peculiar synergetic effect of MoS2 quantum dots and graphene on Metal-Organic Frameworks for photocatalytic hydrogen evolution".Applied Catalysis B: Environmental 210(2017):45-56.
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