| Cobalt-Catalyzed Intramolecular Oxidative C(sp(3))-H/N-H Carbonylation of Aliphatic Amides | |
| Department | OSSO国家重点实验室 |
| Zeng, Li1; Tang, Shan1; Wang, Dan1; Deng, Yi1; Chen, Jeng-Lung3; Jyh-Fu Lee3; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2017 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 19Issue:8Pages:2170-2173 |
| Abstract | A cobalt-catalyzed reaction protocol is developed to achieve the intramolecular oxidative C(sp3)–H/N–H carbonylation of aliphatic amides with CO. Various substituted propanamides are selectively transformed into corresponding succinimides in good to high yields. Notably, predominant selectivity for the carbonylation at the α-methyl groups of linear aliphatic amides is observed in this reaction system. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.orglett.7b00825 |
| Funding Organization | the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities and the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 6.579 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22169 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan |
| Recommended Citation GB/T 7714 | Zeng, Li,Tang, Shan,Wang, Dan,et al. Cobalt-Catalyzed Intramolecular Oxidative C(sp(3))-H/N-H Carbonylation of Aliphatic Amides[J]. Organic Letters,2017,19(8):2170-2173. |
| APA | Zeng, Li.,Tang, Shan.,Wang, Dan.,Deng, Yi.,Chen, Jeng-Lung.,...&雷爱文.(2017).Cobalt-Catalyzed Intramolecular Oxidative C(sp(3))-H/N-H Carbonylation of Aliphatic Amides.Organic Letters,19(8),2170-2173. |
| MLA | Zeng, Li,et al."Cobalt-Catalyzed Intramolecular Oxidative C(sp(3))-H/N-H Carbonylation of Aliphatic Amides".Organic Letters 19.8(2017):2170-2173. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.orglett.7b00825.（950KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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