| Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites | |
| Department | 绿色化学研究发展中心 |
Ma YB(马昱博); He YD(何昱德) ; Zhang QH(张庆华); Shi F(石峰); Ma XY(马祥元); Lu LJ(卢六斤); Deng YQ(邓友全)
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| 2010 | |
| Source Publication | Chinese Journal of Catalysis
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| ISSN | 0253-9837 |
| Volume | 31Issue:8Pages:933-937 |
| Abstract | The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3 000 to 23 000 h–1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis. |
| Keyword | Active Site Ionic Liquid Metal Complex Carbonylation Aniline Phenyl Methyl Carbamate Turnover Frequency |
| Subject Area | 物理化学 |
| Indexed By | CSCD |
| Language | 英语 |
| Funding Project | 绿色催化课题 |
| Citation statistics |
Cited Times:1[CSCD]
[CSCD Record]
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| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2208 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Shi F(石峰); Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Ma YB,He YD,Zhang QH,et al. Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites[J]. Chinese Journal of Catalysis,2010,31(8):933-937. |
| APA | 马昱博.,何昱德.,张庆华.,石峰.,马祥元.,...&邓友全.(2010).Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites.Chinese Journal of Catalysis,31(8),933-937. |
| MLA | 马昱博,et al."Self-Assembly of Ionic Liquids and Metal Complexes in Super-Cages of NaY: Integration of Free Catalysts and Solvent Molecules into Confined Catalytic Sites".Chinese Journal of Catalysis 31.8(2010):933-937. |
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