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Rheological and tribological properties of Ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes
Department固体润滑国家重点实验室
Wang BG(王宝刚); Wang XB(王晓波); Lou WJ(娄文静); Hao JC(郝京诚)
2010
Source PublicationJournal of Physical Chemistry C
ISSN1932-7447
Volume114Issue:19Pages:8749–8754
AbstractRoom temperature ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes(F-MWCNTs) were fabricated. Transmission electron microscopy (TEM), field emission scanning electronmicroscopy (FE-SEM), Fourier transform infrared (FT-IR), and X-ray photoelectron spectra revealed themorphology and chemical structure of the obtained F-MWCNTs. The rheological behaviors of the F-MWCNTs/1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]) nanofluids were studied, demonstrating theshear thinning behavior of nanofluids at rather low concentrations, which could be due to the high specificratio, flexibility of F-MWCNTs, and the formation of a transient network through nanotube nanotube andnanotube matrix interactions. It was found that the rheological behavior of the F-MWCNTs (0.1 wt %)/[Bmim][PF6] nanofluid was similar to that of the surfactant worm-like micelle systems. Therefore, the transientnetwork structure of the F-MWCNTs (0.1 wt %)/[Bmim][PF6] nanofluid could be renovated in a short timeafter shearing forces were input. The shear viscosity of the nanofluids was even lower than that of pure[Bmim][PF6], especially under high shear rates, which could be attributed to the self-lubrication of F-MWCNTs.The tribological properties of the nanofluids were also evaluated in comparison with those of pure [Bmim][PF6]under loads in the range of 200 800 N, indicating that the nanofluids exhibited preferable friction-reductionproperties under 800 N and remarkable antiwear properties with use of reasonable concentrations.
Subject Area材料科学与物理化学
Funding Organizationthe NFSC (Grant No. 20803087);the Major State Basic Research Development Program of China (973Program)(GrantNo.2007CB607606);the Knowledge Innovation Program of the Chinese Academy of Sciences
Indexed BySCI
Language英语
Funding Project工业润滑研究组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/2204
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorHao JC(郝京诚)
Recommended Citation
GB/T 7714
Wang BG,Wang XB,Lou WJ,et al. Rheological and tribological properties of Ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes[J]. Journal of Physical Chemistry C,2010,114(19):8749–8754.
APA 王宝刚,王晓波,娄文静,&郝京诚.(2010).Rheological and tribological properties of Ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes.Journal of Physical Chemistry C,114(19),8749–8754.
MLA 王宝刚,et al."Rheological and tribological properties of Ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes".Journal of Physical Chemistry C 114.19(2010):8749–8754.
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