A novel molybdenum disulfide nanosheet self-assembled flower-like monolithic sorbent for solid-phase extraction with high efficiency and long service life | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Ran, Fanpeng1,2; Liu, Hongmei1; Wang, Xiaoqi1; Guo Y(郭勇)2; Guo Y(郭勇) | |
2017 | |
Source Publication | Journal of Chromatography A |
ISSN | 0021-9673 |
Volume | 1507Pages:18-24 |
Abstract | A novel material consisting of molybdenum disulfide (MoS2) nanosheet that self-assemble into flower-like microspheres which aggregate to form a monolithic matrix with a micro or nano-scaled mesopore structure was successfully synthesized and used as an efficient sorbent for solid-phase extraction (SPE) due to its large specific adsorption area and good stability. The extraction properties of the as-prepared sorbent were evaluated by high-performance liquid chromatography with variable wavelength detection (HPLC-VWD) by analyzing four flavonoids (apigenin, quercetin, luteolin, and kaempferol). Under optimal conditions, the LODs and LOQs were found to be in the ranges of 0.1-0.25 and 0.4-0.5 μgL-1, respectively, and wide linear ranges were obtained with correlation coefficients (R) ranging from 0.9991 to 0.9996. Compared with commercial C18 and Alumina-N sorbents, the as-prepared sorbent showed high extraction efficiency at different concentrations of flavonoids. After 100 uses, the extraction ability of the self-assembled MoS2 nanosheet monolithic sorbent had no evident decline, denoting a long service life. Finally, the SPE-HPLC-VWD method using the as-prepared sorbent was applied to flavonoid analysis in beverage samples with satisfactory results. |
Keyword | Solid Phase Extraction Mos2 Flavonoids High Extraction Efficiency Long Service Life |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.chroma.2017.05.018 |
Funding Organization | the National Natural Science Foundation of China (No. 21665014) |
Indexed By | SCI |
If | 3.981 |
Language | 英语 |
Funding Project | 药物分离材料研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22034 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Liu, Hongmei; Guo Y(郭勇) |
Affiliation | 1.School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730000, China 2.CAS Key Laboratory of Chemistry of Northwestern Plant Resources, Lanzhou Institute of Chemical physics, Chinese Academy of Sciences, Lanzhou 730000,China |
Recommended Citation GB/T 7714 | Ran, Fanpeng,Liu, Hongmei,Wang, Xiaoqi,et al. A novel molybdenum disulfide nanosheet self-assembled flower-like monolithic sorbent for solid-phase extraction with high efficiency and long service life[J]. Journal of Chromatography A,2017,1507:18-24. |
APA | Ran, Fanpeng,Liu, Hongmei,Wang, Xiaoqi,Guo Y,&郭勇.(2017).A novel molybdenum disulfide nanosheet self-assembled flower-like monolithic sorbent for solid-phase extraction with high efficiency and long service life.Journal of Chromatography A,1507,18-24. |
MLA | Ran, Fanpeng,et al."A novel molybdenum disulfide nanosheet self-assembled flower-like monolithic sorbent for solid-phase extraction with high efficiency and long service life".Journal of Chromatography A 1507(2017):18-24. |
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