Water splitting by CdS/Pt/WO3-CeOx photocatalysts with assisting of artificial blood perfluorodecalin | |
Department | OSSO国家重点实验室 |
Tian B(田彬)1,2; Yang BJ(杨宝军)1; Li, Jian3; Li Z(李振)1,2; Zhen WL(甄文龙)1; Wu YQ(吴玉琪)1; Lu GX(吕功煊)1; Lv GX(吕功煊) | |
2017 | |
Source Publication | Journal of Catalysis |
ISSN | 0021-9517 |
Volume | 350Pages:189-196 |
Abstract | Photocatalytic hydrogen production from water splitting is an attractive scientific and technological route to address the increasing global demand for clean energy and to reduce the climate change impact of CO2 emission. Although tremendous efforts have been made, hydrogen generation from pure water by an efficient semiconductor catalyst driven by visible light still remains a significant challenge. Herein we present an effective photocatalyst based on Ce-doped WO3 and CdS powders embedded into platinum (Pt) layer. With the help of artificial blood component perfluorodecalin (PFDL), our system achieved 186.2 μmol.gcatalyst-1 H2 in 4 h without sacrifice reagent under visible light irradiation and maintained excellent stability in 24 h without obvious decay. The hydrogen evolution activity and excellent stability are assigned to the enhancement of the electrons and holes relay and transfer by Pt layer, and the removal of nascent oxygen from catalyst via CeO2 and artificial blood PFDL path, and the suppression of undesirable hydrogen and oxygen recombination reverse reaction. |
Keyword | Water Splitting Photocatalysts Artificial Blood Perfluorodecalin |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.jcat.2017.03.012 |
Funding Organization | the National Natural Science Foundation of China (Grant Nos. 21433007;21673262) |
Indexed By | SCI |
If | 6.844 |
Language | 英语 |
Funding Project | 环境催化与氢能研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21998 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Lv GX(吕功煊) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.China Astronaut Res & Training Ctr, Beijing 100094, Peoples R China |
Recommended Citation GB/T 7714 | Tian B,Yang BJ,Li, Jian,et al. Water splitting by CdS/Pt/WO3-CeOx photocatalysts with assisting of artificial blood perfluorodecalin[J]. Journal of Catalysis,2017,350:189-196. |
APA | Tian B.,Yang BJ.,Li, Jian.,Li Z.,Zhen WL.,...&吕功煊.(2017).Water splitting by CdS/Pt/WO3-CeOx photocatalysts with assisting of artificial blood perfluorodecalin.Journal of Catalysis,350,189-196. |
MLA | Tian B,et al."Water splitting by CdS/Pt/WO3-CeOx photocatalysts with assisting of artificial blood perfluorodecalin".Journal of Catalysis 350(2017):189-196. |
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1-s2.0-S002195171730(2173KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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