A novel mesoporous sulfated zirconium solid acid catalyst for Friedel-Crafts benzylation reaction | |
Department | OSSO国家重点实验室 |
Miao ZC(苗智超)1; Zhou, Jin1; Zhao, Jinping1; Liu, Dandan1; Bi, Xu1; Chou LJ(丑凌军)2; Zhuo, Shuping1; Chou LJ(丑凌军) | |
2017 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 411Pages:419-430 |
Abstract | In this paper, a novel mesoporous sulfated zirconium (M-ZrO2/SO42−) has been gotten by one-pot evaporation-induced self-assembly (one-pot EISA) strategy. The SXRD, N2-physisorption and TEM characterization techniques indicated that M-ZrO2/SO42− possessed distinct mesostructure with big specific surface area (133.5 m2 g−1), large pore volume (0.18 cm3 g−1) and narrow pore size distribution (4.90 nm). Moreover, the existing states and the influence in mesostructure of introduced S species were detailedly investigated by the XRD, N2-physisorption, TEM, TG-DSC, FT-IR and XPS techniques and the results showed that the S species, which existed as the type of SO42−, improved the textural properties of prepared materials. In addition, the NH3-TPD and IR spectra of adsorbed pyridine indicated the existence of strong Brønsted and Lewis acid sites in M-ZrO2/SO42− even evacuated at 400 °C. Furthermore, the M-ZrO2/SO42− was used as a promise solid acid catalyst and displayed excellent catalytic performance and reusability in Friedel-Crafts benzylation reaction. |
Keyword | One-pot Sulfated Zirconium Mesostructure Solid Acid Friedel-crafts Benzylation |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.apsusc.2017.03.183 |
Funding Organization | the NSFC 21373244;21576158;21576159 |
Indexed By | SCI |
If | 3.387 |
Language | 英语 |
Funding Project | 多相催化-1研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21887 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Zhuo, Shuping; Chou LJ(丑凌军) |
Affiliation | 1.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Miao ZC,Zhou, Jin,Zhao, Jinping,et al. A novel mesoporous sulfated zirconium solid acid catalyst for Friedel-Crafts benzylation reaction[J]. Applied Surface Science,2017,411:419-430. |
APA | Miao ZC.,Zhou, Jin.,Zhao, Jinping.,Liu, Dandan.,Bi, Xu.,...&丑凌军.(2017).A novel mesoporous sulfated zirconium solid acid catalyst for Friedel-Crafts benzylation reaction.Applied Surface Science,411,419-430. |
MLA | Miao ZC,et al."A novel mesoporous sulfated zirconium solid acid catalyst for Friedel-Crafts benzylation reaction".Applied Surface Science 411(2017):419-430. |
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