| Visible-light-mediated C2-amination of thiophenes by using DDQ as an organophotocatalyst | |
| Department | OSSO国家重点实验室 |
| Song, Chunlan1; Yi, Hong1; Dou, Bowen1; Li, Yiying1; Atul K. Singh1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2017 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 53Issue:26Pages:3689-3692 |
| Abstract | In this work, a direct C–H activation of thiophenes was presented via an oxidation pathway under visible-light irradiation, in which the thiophene radical cation serves as the key intermediate. Various thiophenes and azoles could be transformed into the corresponding amination products well, and H2O was the only byproduct which is environmentally benign. Our results showed that tert-butyl nitrite (TBN) served as the electron transfer mediator and O2 as the terminal oxidant to regenerate the photocatalyst DDQ and revive the photocatalytic cycle. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c7cc01339f |
| Funding Organization | the National Natural Science Foundation of China (21390400;21520102003;21272180;21302148);the HubeiProvince Natural Science Foundation of China (2013CFA081);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Ministry of Science and Technology of China (2012YQ120060);the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 6.319 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21790 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Song, Chunlan,Yi, Hong,Dou, Bowen,et al. Visible-light-mediated C2-amination of thiophenes by using DDQ as an organophotocatalyst[J]. Chemical Communications,2017,53(26):3689-3692. |
| APA | Song, Chunlan.,Yi, Hong.,Dou, Bowen.,Li, Yiying.,Atul K. Singh.,...&雷爱文.(2017).Visible-light-mediated C2-amination of thiophenes by using DDQ as an organophotocatalyst.Chemical Communications,53(26),3689-3692. |
| MLA | Song, Chunlan,et al."Visible-light-mediated C2-amination of thiophenes by using DDQ as an organophotocatalyst".Chemical Communications 53.26(2017):3689-3692. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c7cc01339f.pdf（2220KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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