Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores

doi:10.1002/chem.201605793

	Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores
Department	OSSO国家重点实验室
	Huang, Jiang-Bo 1; Bai, Xing-Feng 1; Li, Li 1; Zheng, Zhan-Jiang 1; Xu, Zheng 1; Cui, Yu-Ming 1; Cao, Jian 1; Xu LW(徐利文)1,2; Xu LW(徐利文)
	2017
Source Publication	Chemistry - A European Journal
ISSN	0947-6539
Volume	23 Issue:17 Pages:4055-4059
Abstract	Direct functionalization of terpyridines is an increasingly important topic in the field of dyes and catalysis as well as supramolecular chemistry, but its synthesis and transformation is usually challenging. Herein, a HOMO-raising strategy is reported for the construction of a super-stable novel terpyridine chromophores, in which the selective oxidation of terpyridines at its 3-position was determined successfully to the synthesis of phenol-functionalization of terpyridines (TPyOHs) bearing a hydrogen bonding group. The corresponding TPyOHs displayed strong aggregation-induced emission and exhibited highly selective and visual detection of Zn^II cation with a record green terpyridine-based luminophore with nanomolar sensitivity (125 nm).
Keyword	Aggregation-induced Emission Lithium Molecular Recognition Selective Oxidation Terpyridine
Subject Area	物理化学与绿色催化
DOI	10.1002/chem.201605793
Funding Organization	the National Natural Science Founder of China (No. 21472031;21503060); Zhejiang Provincial Natural Science Foundation of China (LY17E030003;LY17B030005); Science and Technology Department of Zhejiang Province (2015C31138);Hangzhou Science and Technology Bureau of China (20170533B08;20160432B08)
Indexed By	SCI
If	5.317
Language	英语
compositor	第二作者单位
Citation statistics	Cited Times:4[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/21779
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Xu, Zheng; Xu LW(徐利文)
Affiliation	1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Beijing, Peoples R China
Recommended Citation GB/T 7714	Huang, Jiang-Bo,Bai, Xing-Feng,Li, Li,et al. Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores[J]. Chemistry - A European Journal,2017,23(17):4055-4059.
APA	Huang, Jiang-Bo.,Bai, Xing-Feng.,Li, Li.,Zheng, Zhan-Jiang.,Xu, Zheng.,...&徐利文.(2017).Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores.Chemistry - A European Journal,23(17),4055-4059.
MLA	Huang, Jiang-Bo,et al."Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores".Chemistry - A European Journal 23.17(2017):4055-4059.

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