| Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling | |
| Department | OSSO国家重点实验室 |
| Wang, Pan1; Tang, Shan1; Huang, Pengfei1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2017 | |
| Source Publication | Angewandte Chemie International Edition
 |
| ISSN | 1433-7851 |
| Volume | 56Issue:11Pages:3009-3013 |
| Abstract | An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C-H/S-H crosscoupling. This method enabled C-S bond formation under catalyst-and oxidant-free conditions. Under undivided electrolysis conditions, various aryl/heteroaryl thiols and electronrich arenes afforded the C-S bond-formation products in 24-99% yield. A preliminary mechanistic study indicated that the generation of aryl radical cation intermediates is key to the success of this transformation. |
| Keyword | C-h Functionalization C-s Bond Formation Dehydrogenation Electrochemistry Radical Cations |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/anie.201700012 |
| Funding Organization | the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities;the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 11.994 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21644 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Pan,Tang, Shan,Huang, Pengfei,et al. Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling[J]. Angewandte Chemie International Edition,2017,56(11):3009-3013. |
| APA | Wang, Pan,Tang, Shan,Huang, Pengfei,Lei AW,&雷爱文.(2017).Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling.Angewandte Chemie International Edition,56(11),3009-3013. |
| MLA | Wang, Pan,et al."Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling".Angewandte Chemie International Edition 56.11(2017):3009-3013. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Wang_et_al-2017-Ange（848KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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