Asymmetric Epoxidation of Olefins with H2O2 Catalyzed by a Bioinspired Aminopyridine N4 Iron Complex | |
Department | OSSO国家重点实验室 |
Wang WF(王文芳)1,2,3; Sun QS(孙强盛)1,2; Xu DQ(徐大乾)1,2; Xia CG(夏春谷)1,2; Sun W(孙伟)1,2; Sun W(孙伟) | |
The second department | 苏州研究院 |
2017 | |
Source Publication | ChemCatChem |
ISSN | 1867-3880 |
Volume | 9Issue:3Pages:420-424 |
Abstract | An iron complex with a chiral aminopyridine N4 ligand bearing strong electron-donating and bulky morpholine groups on the ligand is synthesized and characterized. The iron complex serves to efficiently catalyze the asymmetric epoxidation of various olefins by employing aqueous hydrogen peroxide as the green oxidant, providing the corresponding epoxides in good to excellent yields and enantioselectivities (up to 93 % yield and 99.9 % ee). Owing to the introduction of morpholine functional groups on the ligand, the Fe-catalyzed reaction can proceed with a catalytic amount of the carboxylic acid partner (3 mol %). |
Keyword | Asymmetric Epoxidation Bioinspired Catalysis Hydrogen Peroxide Iron Olefins |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/cctc.201601293 |
Funding Organization | the National Natural Science Foundation of China (21473226;21133011) |
Indexed By | SCI |
If | 4.803 |
Language | 英语 |
Funding Project | 仿生与生物催化研究组;均相催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21608 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 苏州研究院 |
Corresponding Author | Sun W(孙伟) |
Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, LICP, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Suzhou Res Inst, LICP, Lanzhou 730000, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Wang WF,Sun QS,Xu DQ,et al. Asymmetric Epoxidation of Olefins with H2O2 Catalyzed by a Bioinspired Aminopyridine N4 Iron Complex[J]. ChemCatChem,2017,9(3):420-424. |
APA | Wang WF,Sun QS,Xu DQ,Xia CG,Sun W,&孙伟.(2017).Asymmetric Epoxidation of Olefins with H2O2 Catalyzed by a Bioinspired Aminopyridine N4 Iron Complex.ChemCatChem,9(3),420-424. |
MLA | Wang WF,et al."Asymmetric Epoxidation of Olefins with H2O2 Catalyzed by a Bioinspired Aminopyridine N4 Iron Complex".ChemCatChem 9.3(2017):420-424. |
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LZ01029960.pdf(619KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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