| Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane | |
| Department | OSSO国家重点实验室 |
Ren XY(任新意)1,2; Zheng, Zhiyao2; Zhang, Lei2; Wang, Zheng2; Xia CG(夏春谷)1 ; Ding KL(丁奎岭)2,3; Xia CG(夏春谷); Ding KL(丁奎岭)
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| 2017 | |
| Source Publication | Angewandte Chemie International Edition
 |
| ISSN | 1433-7851 |
| Volume | 56Issue:1Pages:310-313 |
| Abstract | A rhodium-catalyzed one-pot hydroformylation of olefins with CO2 , hydrosilane, and H2 has been developed that affords the aldehydes in good chemoselectivities at low catalyst loading. Mechanistic studies indicate that the transformation is likely to proceed through a tandem sequence of poly(methylhydrosiloxane) (PMHS) mediated CO2 reduction to CO and a conventional rhodium-catalyzed hydroformylation with CO/H2. The hydrosilylane-mediated reduction of CO2 in preference to aldehydes was found to be crucial for the selective formation of aldehydes under the reaction conditions. |
| Keyword | Aldehydes Carbondi Oxide Hydroformylation Olefins Rhodium |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/anie.201608628 |
| Funding Organization | MOST (2016YFA0202900);the National Natural Science Foundation of China (21421091;21572254);the Chinese Academy of Sciences;the Science and Technology Commission of Shanghai Municipality |
| Indexed By | SCI |
| If | 11.994 |
| Language | 英语 |
| Funding Project | 均相催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21543 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Ding KL(丁奎岭) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Ren XY,Zheng, Zhiyao,Zhang, Lei,et al. Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane[J]. Angewandte Chemie International Edition,2017,56(1):310-313. |
| APA | Ren XY.,Zheng, Zhiyao.,Zhang, Lei.,Wang, Zheng.,Xia CG.,...&丁奎岭.(2017).Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane.Angewandte Chemie International Edition,56(1),310-313. |
| MLA | Ren XY,et al."Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane".Angewandte Chemie International Edition 56.1(2017):310-313. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Ren_et_al-2017-Angew（614KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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