LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides
DepartmentOSSO国家重点实验室
Lai, Yi1; Zong, Zhijian1; Tang, Yujie1; Mo WM(莫卫民)1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Jin, Liqun1,2; Sun WH(孙文华)3; Hu XQ(胡信全)1,2; Sun WH(孙文华); Hu XQ(胡信全)
2017
Source PublicationBeilstein Journal of Organic Chemistry
ISSN1860-5397
Volume13Pages:213-221
Abstract

A series of bulky geometry-constrained iminopyridylpalladium chlorides were developed. The steric environment adjacent to the nitrogen atom in the pyridine rings and diimine parts enhanced the thermal stability of the palladium species. Bulkier groups at the imino group stabilized the palladium species and the corresponding palladium chlorides showed high activities in the coupling reaction of aryl chlorides.

KeywordAryl Chloride Geometry-constrained Iminopyridyl Palladium Suzuki
Subject Area物理化学与绿色催化
DOI10.3762/bjoc.13.24
Funding Organizationthe National Natural Science Foundations of China (21473160;21376224;21603190);Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province
Indexed BySCI
If2.337
Language英语
compositor第二作者单位
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21542
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorJin, Liqun; Sun WH(孙文华); Hu XQ(胡信全)
Affiliation1.College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, P.R. China
2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P.R. China
3.Key laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China
Recommended Citation
GB/T 7714
Lai, Yi,Zong, Zhijian,Tang, Yujie,et al. Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides[J]. Beilstein Journal of Organic Chemistry,2017,13:213-221.
APA Lai, Yi.,Zong, Zhijian.,Tang, Yujie.,Mo WM.,Sun N.,...&胡信全.(2017).Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides.Beilstein Journal of Organic Chemistry,13,213-221.
MLA Lai, Yi,et al."Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides".Beilstein Journal of Organic Chemistry 13(2017):213-221.
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