Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides | |
Department | OSSO国家重点实验室 |
Lai, Yi1; Zong, Zhijian1; Tang, Yujie1; Mo WM(莫卫民)1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Jin, Liqun1,2; Sun WH(孙文华)3; Hu XQ(胡信全)1,2; Sun WH(孙文华); Hu XQ(胡信全) | |
2017 | |
Source Publication | Beilstein Journal of Organic Chemistry |
ISSN | 1860-5397 |
Volume | 13Pages:213-221 |
Abstract | A series of bulky geometry-constrained iminopyridylpalladium chlorides were developed. The steric environment adjacent to the nitrogen atom in the pyridine rings and diimine parts enhanced the thermal stability of the palladium species. Bulkier groups at the imino group stabilized the palladium species and the corresponding palladium chlorides showed high activities in the coupling reaction of aryl chlorides. |
Keyword | Aryl Chloride Geometry-constrained Iminopyridyl Palladium Suzuki |
Subject Area | 物理化学与绿色催化 |
DOI | 10.3762/bjoc.13.24 |
Funding Organization | the National Natural Science Foundations of China (21473160;21376224;21603190);Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province |
Indexed By | SCI |
If | 2.337 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21542 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Jin, Liqun; Sun WH(孙文华); Hu XQ(胡信全) |
Affiliation | 1.College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, P.R. China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P.R. China 3.Key laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China |
Recommended Citation GB/T 7714 | Lai, Yi,Zong, Zhijian,Tang, Yujie,et al. Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides[J]. Beilstein Journal of Organic Chemistry,2017,13:213-221. |
APA | Lai, Yi.,Zong, Zhijian.,Tang, Yujie.,Mo WM.,Sun N.,...&胡信全.(2017).Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides.Beilstein Journal of Organic Chemistry,13,213-221. |
MLA | Lai, Yi,et al."Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides".Beilstein Journal of Organic Chemistry 13(2017):213-221. |
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1860-5397-13-24.pdf(633KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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