Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones | |
Department | OSSO国家重点实验室 |
Shi, Renyi1; Niu, Huiying1; Lu, Lijun1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
2017 | |
Source Publication | Chemical Communications |
ISSN | 1359-7345 |
Volume | 53Issue:11Pages:1908-1911 |
Abstract | It is important to achieve diverse functionalization of tertiary anilines due to their importance in biological molecules, pharmaceutical, functional materials, and ligands. A straightforward Pd/Cu-catalyzed oxidative C–H bond activation/N-dealkylative carbonylation of tertiary [1,1′-biphenyl]-2-anilines towards the synthesis of various biologically important phenanthridin-6(5H)-ones has been developed. A wide range of functional groups are well tolerated in this transformation. Moreover, O2 is utilized as the terminal oxidant to promote the oxidative carbonylation process. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c6cc08701a |
Funding Organization | the National Natural Science Foundation of China (21390400;21520102003;21272180;21302148);the Hubei Province Natural Science Foundation of China (2013CFA081);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Ministry of Science and Technology of China (2012YQ120060);the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
Indexed By | SCI |
If | 6.319 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21525 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Lei AW(雷爱文) |
Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Shi, Renyi,Niu, Huiying,Lu, Lijun,et al. Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones[J]. Chemical Communications,2017,53(11):1908-1911. |
APA | Shi, Renyi,Niu, Huiying,Lu, Lijun,Lei AW,&雷爱文.(2017).Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones.Chemical Communications,53(11),1908-1911. |
MLA | Shi, Renyi,et al."Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones".Chemical Communications 53.11(2017):1908-1911. |
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c6cc08701a.pdf(2107KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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