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Efficient Removal of Methyl Orange and Alizarin Red S from pH-Unregulated Aqueous Solution by the Catechol-Amine Resin Composite Using Hydrocellulose as Precursor
Department固体润滑国家重点实验室
Liu, Qiang1; Liu QZ(刘钦泽)1; Wu, Zhuotong1; Wu Y(吴杨)3; Gao TT(高婷婷)2; Yao, Jinshui1; Liu QZ(刘钦泽)
2017
Source PublicationACS Sustainable Chemistry and Engineering
ISSN2168-0485
Volume5Issue:2Pages:1871-1880
Abstract

We report a novel composite absorbent prepared by the simple method that catechol-amine resin coats the hydrocellulose based on the adhesion property like polydopamine. The composite which contains many chelating groups on its surface was characterized by scanning electron microscopy (SEM), infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), etc. The obtained adsorbents were investigated to remove Methyl Orange (MO) and Alizarin Red S (AR) from pH-unregulated aqueous system by batch experiments, including the affected factors of adsorbent dosage, contact time, initial concentration, and temperature. Results showed the adsorption processes belonged to the chemisorption and exhibited a spontaneous and endothermic nature. Besides, the removal performances fitted with the Langmuir isotherm model and pseudo-second order kinetic model very well. The maximum adsorption amounts of MO and AR were 189.39 and 284.09 mg/g at 303 K, respectively. The difference about adsorption amounts may be caused by the strong effect of π–π conjugation and hydrogen bonding between adsorbent and AR. Furthermore, the adsorption processes exhibited a spontaneous and endothermic nature. The recycling test indicated that the adsorbent stayed stable for the removal of both dyes by desorbed three times. Accordingly, the adsorbent with high adsorption capacity and rapid removal rate should be a promising material for the removal of anionic dyes from sewage.

KeywordAdhesion Adsorption Alizarin Red s Catechol-amine Resin Composite Methyl Orange
Subject Area材料科学与物理化学
DOI10.1021/acssuschemeng.6b02593
Funding Organizationthe National Natural Science Foundation of China (Grant Nos. 51303086;51503108);Natural Science Foundation of Shandong Province (Grant No. ZR2013EMQ005);
Indexed BySCI
If5.951
Language英语
compositor第三作者单位
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21474
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorLiu QZ(刘钦泽)
Affiliation1.Qilu Univ Technol, Sch Mat Sci & Engn, Jinan 250353, Peoples R China
2.Qilu Univ Technol, Sch Chem & Pharmaceut Engn, Jinan 250353, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Liu, Qiang,Liu QZ,Wu, Zhuotong,et al. Efficient Removal of Methyl Orange and Alizarin Red S from pH-Unregulated Aqueous Solution by the Catechol-Amine Resin Composite Using Hydrocellulose as Precursor[J]. ACS Sustainable Chemistry and Engineering,2017,5(2):1871-1880.
APA Liu, Qiang.,Liu QZ.,Wu, Zhuotong.,Wu Y.,Gao TT.,...&刘钦泽.(2017).Efficient Removal of Methyl Orange and Alizarin Red S from pH-Unregulated Aqueous Solution by the Catechol-Amine Resin Composite Using Hydrocellulose as Precursor.ACS Sustainable Chemistry and Engineering,5(2),1871-1880.
MLA Liu, Qiang,et al."Efficient Removal of Methyl Orange and Alizarin Red S from pH-Unregulated Aqueous Solution by the Catechol-Amine Resin Composite Using Hydrocellulose as Precursor".ACS Sustainable Chemistry and Engineering 5.2(2017):1871-1880.
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