Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source | |
Department | OSSO国家重点实验室 |
Cao, Jian1; Zheng, Zhan-Jiang1; Xu, Zheng1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
2017 | |
Source Publication | Coordination Chemistry Reviews |
ISSN | 0010-8545 |
Volume | 336Pages:43-53 |
Abstract | While carbon monoxide (CO) gas has been extensively applied in the bulk chemical industry, its intrinsic properties such as high toxicity, flammability, and special equipment requirement for handling, limit its utilization in organic synthesis, fine chemical industry and academia. Recently, considerable effort has been devoted to the development of CO surrogates to avoid the direct use of carbon monoxide gas. Among the various CO surrogates, formic acid and formaldehyde, have a broad range of applications in organic synthesis. The direct carbonylation with formic acid (HCOOH) and formaldehyde (HCHO) represents one of the most atom-economical substitutes owing to their high weight percentage of CO. In this review, the potential roles of both formic acid and formaldehyde in transition-metal catalyzed carbonylation reactions are discussed. In order to understand these transfer carbonylation reactions, the mechanistic rationale for representative examples is also provided. |
Keyword | Carbonylation Transition-metal Catalysis Non-gaseous C1 Source Co Surrogates |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.ccr.2017.01.005 |
Funding Organization | the National Natural Science Founder of China (No. 51303043;21472031;21503060);Zhejiang Provincial Natural Science Foundation of China (LR14B030001;LY14B020013);Science and Technology Department of Zhejiang Province (2015C31138);Hangzhou Science and Technology Bureau of China (20140432B04) |
Indexed By | SCI |
If | 13.324 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21469 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Cao, Jian; Xu LW(徐利文) |
Affiliation | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Cao, Jian,Zheng, Zhan-Jiang,Xu, Zheng,et al. Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source[J]. Coordination Chemistry Reviews,2017,336:43-53. |
APA | Cao, Jian,Zheng, Zhan-Jiang,Xu, Zheng,Xu LW,&徐利文.(2017).Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source.Coordination Chemistry Reviews,336,43-53. |
MLA | Cao, Jian,et al."Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source".Coordination Chemistry Reviews 336(2017):43-53. |
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