The influences of methyl group at C2 position in imidazolium ring on tribological properties | |
Department | 固体润滑国家重点实验室 |
Zhang HB(张浩波); Xia YQ(夏延秋); Yao MH(姚美焕); Jia ZF(贾正锋); Liu ZL(刘志鲁) | |
2009 | |
Source Publication | Tribology Letters |
ISSN | 1023-8883 |
Volume | 36Pages:105-111 |
Abstract | Tribological properties of two kinds of imidazolium ionic liquids (ILs) of 1,2-dimethyl-3-hexylimidazolium bis(trifluoromethylsulfonyl)imide (L-F116) and 1-dimethyl-3-hexylimidazolium bis(trifluoromethyl- sulfonyl)imide (L-F106) were evaluated as lubricant additives in poly(ethylene glycol) (PEG) for the steel–steel sliding pair by using an Optimol-SRV oscillating friction and wear test at the room temperature. At the same time, their electrochemical corrosion behaviors were measured by Tafel polarization. The morphologies of the worn surfaces were observed using a scanning electron microscope (SEM). The chemical states of several typical elements on the worn surfaces were examined by means of X-ray photoelectron spectroscopy (XPS). The results show that corrosion phenomena of PEG containing ILs on pure copper are negligible compared to PEG at room temperature. The 2-substituted imidazolium IL L-F116 shows excellent tribological performance and is superior to L-F106 in terms of anti-wear performance and load-carrying capacity. The worn surfaces were characterized to have slight abrasion and the XPS results indicated the formation of tribochemical adsorption and chemical reaction films on the worn surfaces. |
Keyword | Ionic Liquids Additives Tribology High Performance Lubricant |
Subject Area | 材料科学与物理化学 |
Funding Organization | “Hundred Talents Program” of CAS;NSFC (20533080);KJCX2.YW.H16 |
Indexed By | SCI |
Language | 英语 |
Funding Project | 空间润滑材料组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2145 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Xia YQ(夏延秋) |
Recommended Citation GB/T 7714 | Zhang HB,Xia YQ,Yao MH,et al. The influences of methyl group at C2 position in imidazolium ring on tribological properties[J]. Tribology Letters,2009,36:105-111. |
APA | 张浩波,夏延秋,姚美焕,贾正锋,&刘志鲁.(2009).The influences of methyl group at C2 position in imidazolium ring on tribological properties.Tribology Letters,36,105-111. |
MLA | 张浩波,et al."The influences of methyl group at C2 position in imidazolium ring on tribological properties".Tribology Letters 36(2009):105-111. |
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