| Regio- and Stereoselective Allylic C-H Arylation with Electron-Deficient Arenes by 1,1 '-Bi-2-naphthol-Palladium Cooperation | |
| Department | OSSO国家重点实验室 |
| Wang, Gang-Wei1; Zhou, An-Xi1; Li, Shi-Xia1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
| 2014 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 16Issue:11Pages:3118-3121 |
| Abstract | A palladium-catalyzed allylic C–H arylation reaction with electron-deficient arenes with high regio- and stereoselectivity is reported. This work represents the first successful use of 1,1′-bi-2-naphthol as the ancillary ligand in allylic C–H activation, which is the key factor for chemoselectivity. Furthermore, high selectivity allylic C–H acetoxylation and amination were also successfully achieved under the same catalytic system. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ol501247b |
| Funding Organization | the NSFC (No. 21272100);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07) |
| Indexed By | SCI |
| If | 6.364 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21327 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang SD(杨尚东) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Gang-Wei,Zhou, An-Xi,Li, Shi-Xia,et al. Regio- and Stereoselective Allylic C-H Arylation with Electron-Deficient Arenes by 1,1 '-Bi-2-naphthol-Palladium Cooperation[J]. Organic Letters,2014,16(11):3118-3121. |
| APA | Wang, Gang-Wei,Zhou, An-Xi,Li, Shi-Xia,Yang SD,&杨尚东.(2014).Regio- and Stereoselective Allylic C-H Arylation with Electron-Deficient Arenes by 1,1 '-Bi-2-naphthol-Palladium Cooperation.Organic Letters,16(11),3118-3121. |
| MLA | Wang, Gang-Wei,et al."Regio- and Stereoselective Allylic C-H Arylation with Electron-Deficient Arenes by 1,1 '-Bi-2-naphthol-Palladium Cooperation".Organic Letters 16.11(2014):3118-3121. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ol501247b.pdf（1230KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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