Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil

doi:10.1016/j.triboint.2014.01.006

	Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil
Department	固体润滑国家重点实验室
	Li, Jianchang 1,2,3; Li, Zhipeng 1; Ren TH(任天辉)1; Zeng, Xiangqiong 3; Emeil van der Heide 3,4; Ren TH(任天辉)
	2014
Source Publication	Tribology International
ISSN	0301-679X
Volume	73 Pages:101-107
Abstract	Borate ester compounds are emerging as promising materials for lubricating systems. The main drawback of borate esters however, is the susceptiblity to hydrolysis. In this work, two kinds of N-containing heterocyclic borate esters were synthesized. Their hydrolytic stability and tribological properties as lubricant additives in rapeseed oil were evaluated. The results showed that these borate esters not only possessed promising tribological properties, but also had high hydrolytic stability. Thermal films and tribofilms were investigated by using X-ray absorption near-edge structure (XANES) spectroscopy. Surface analysis indicated that thermal films were mainly composed of adsorbed films and thermo-chemical reaction products. Tribofilms were mainly constituted by BN, B₂O₃ and organic B.
Keyword	Heterocyclic Borate Esters Hydrolytic Stability Tribological Properties Xanes Spectroscopy
Subject Area	材料科学与物理化学
DOI	10.1016/j.triboint.2014.01.006
Funding Organization	the National Natural Science Foundation of China (Grant no. 21272157);Beijing Synchrotron Radiation Facility (Grant no. SR06033);European Union Marie Curie CIG (Grant no. PCIG10-GA-2011–303922);the open projects of The Key State Lab of Solid Lubrication in Lanzhou of China (Grant no. 1205)
Indexed By	SCI
If	1.936
Language	英语
compositor	第二作者单位
Citation statistics	Cited Times:34[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/21309
Collection	固体润滑国家重点实验室（LSL）
Corresponding Author	Ren TH(任天辉)
Affiliation	1.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Thin Film & Microfabricat, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Univ Twente, Lab Surface Technol & Tribol, NL-7500 AE Enschede, Netherlands 4.TNO, Eindhoven, Netherlands
Recommended Citation GB/T 7714	Li, Jianchang,Li, Zhipeng,Ren TH,et al. Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil[J]. Tribology International,2014,73:101-107.
APA	Li, Jianchang,Li, Zhipeng,Ren TH,Zeng, Xiangqiong,Emeil van der Heide,&任天辉.(2014).Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil.Tribology International,73,101-107.
MLA	Li, Jianchang,et al."Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil".Tribology International 73(2014):101-107.

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