Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature | |
Department | OSSO国家重点实验室 |
Han, Wenjia2; Zhang GY(张国营)1; Li, Guangxing2; Huang HM(黄汉民)1; Huang HM(黄汉民) | |
2014 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 16Issue:13Pages:3532-3535 |
Abstract | A rhodium-catalyzed sequential oxidative C–H annulation reaction between ketazines and internal alkynes has been developed via C–H and N–N bond activation with air as an external oxidant, which led to an efficient approach toward isoquinolines with high atom efficiency at rt. Utilizing the distinctive reactivity of this catalysis, both N-atoms of the azines could be efficiently incorporated to the desired isoquinolines under very robust and mild reaction conditions. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/ol501483k |
Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21133011;21372231) |
Indexed By | SCI |
If | 6.364 |
Language | 英语 |
Funding Project | 有机功能材料研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21303 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Li, Guangxing; Huang HM(黄汉民) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China |
Recommended Citation GB/T 7714 | Han, Wenjia,Zhang GY,Li, Guangxing,et al. Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature[J]. Organic Letters,2014,16(13):3532-3535. |
APA | Han, Wenjia,Zhang GY,Li, Guangxing,Huang HM,&黄汉民.(2014).Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature.Organic Letters,16(13),3532-3535. |
MLA | Han, Wenjia,et al."Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature".Organic Letters 16.13(2014):3532-3535. |
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ol501483k.pdf(470KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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