Preparation and Characterization of Cu2ZnSn(SxSe1-x)(4) Thin Films by Synchronous Sulfo-Selenization of Single-Source Evaporated Metallic Precursors
Department先进润滑与防护材料研究发展中心
Jiang X(姜欣)1,2,3; Shao, Lexi2; Zhang, Jun2; Chen JM(陈建敏)1; Chen JM(陈建敏)
The second department固体润滑国家重点实验室
2014
Source PublicationActa Metallurgica Sinica
ISSN1006-7191
Volume27Issue:4Pages:689-693
Abstract

Cu2ZnSn(S,Se)4 (CZTSSe) thin film was prepared using a simple two-step approach based on the single-source evaporation and synchronous sulfo-selenization. Composition, microstructure, morphology, and properties of the as-prepared CZTSSe thin films were investigated. XRD and Raman patterns confirmed the formation of single-phase CZTSSe solid solutions. SEM results showed that the CZTSSe thin film had a uniform morphology and large grains. EDS results revealed the composition of CZTSSe film was Cu:Zn:Sn:S:Se = 23.7:12.6:12.2:37.7:13.8 (in at%), which was in accordance with the stoichiometric Cu2ZnSn(S,Se)4. The optical band gap of CZTSSe thin film evaluated from its UV–Vis spectrum was 1.33 eV. The resistivity, carrier concentration, and mobility were 0.53 Ω cm, 7.9 × 1018 cm3, and 7.5 cm2/(Vs), respectively.

KeywordEvaporation Cu2znsn(s Sulfo-selenization Se)(4) Thin Film
Subject Area材料科学与物理化学
DOI10.1007/s40195-014-0098-3
Funding Organizationthe National Natural Science Foundation of China (Nos. 51275509;51175491)
Indexed BySCI
If0.727
Language英语
Funding Project磨损与表面工程课题组
compositor第一作者单位
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21254
Collection中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorChen JM(陈建敏)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Zhanjiang Normal Univ, Sch Phys Sci & Technol, Zhanjiang 524048, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jiang X,Shao, Lexi,Zhang, Jun,et al. Preparation and Characterization of Cu2ZnSn(SxSe1-x)(4) Thin Films by Synchronous Sulfo-Selenization of Single-Source Evaporated Metallic Precursors[J]. Acta Metallurgica Sinica,2014,27(4):689-693.
APA Jiang X,Shao, Lexi,Zhang, Jun,Chen JM,&陈建敏.(2014).Preparation and Characterization of Cu2ZnSn(SxSe1-x)(4) Thin Films by Synchronous Sulfo-Selenization of Single-Source Evaporated Metallic Precursors.Acta Metallurgica Sinica,27(4),689-693.
MLA Jiang X,et al."Preparation and Characterization of Cu2ZnSn(SxSe1-x)(4) Thin Films by Synchronous Sulfo-Selenization of Single-Source Evaporated Metallic Precursors".Acta Metallurgica Sinica 27.4(2014):689-693.
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